A sample of a gas at room temperature occupies a volume of 29.0 L at a pressure of 562 torr . If the pressure changes to 2810 to
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Answer : The radii of the two ions Cl⁻ ion and Na⁺ ion is, 181 and 102 pm respectively.
Explanation :
As we are given that the Na⁺ radius is 56.4% of the Cl⁻ radius.
Let us assume that the radius of Cl⁻ be, (x) pm
So, the radius of Na⁺ =
In the crystal structure of NaCl, 2 Cl⁻ ions present at the corner and 1 Na⁺ ion present at the edge of lattice.
Thus, the edge length is equal to the sum of 2 radius of Cl⁻ ion and 2 radius of Na⁺ ion.
Given:
Distance between Na⁺ nuclei = 566 pm
Thus, the relation will be:
The radius of Cl⁻ ion = (x) pm = 181 pm
The radius of Na⁺ ion = (0.564x) pm = (0.564 × 181) pm =102.084 pm ≈ 102 pm
Thus, the radii of the two ions Cl⁻ ion and Na⁺ ion is, 181 and 102 pm respectively.
The question is incomplete. Here is the complete question.
Aqueous solutions of and
, 0.10 M each, are combined. A white precipitate is observed in the container after mixing. he precipitate is filtered andcarefully rinsed with distilled water to remove other ions. A sample of the precipitate is added to 100 mL of 0.1 M NaCl. A second sample of the precipitate is then added to 100 mL of 0.1 M HCl. What would be observed in each case?
Observation upon Observation upon
addition of precipitate addition of precipitate
to NaCl(aq) to HCl(aq)
(A) additional precipitates forms no visible reaction occurs
(B) no visible reaction occurs gas is produced and some precipitate dissolves
(C) no visible reaction occurs no visible reaction occurs
(D) additional precipitates forms gas is produced and some
precipitate dissolves
Answer: (B) No visible reaction occurs; Gas is produced and some precipitate dissolves
Explanation: When aqueous solutions of and
are combined, it reacts according to the following balanced equation:
→
forming calcium carbonate (), which, as it is insoluble in water, precipitates as a solid of the color white. This process is <u>Precipitation</u> and this reaction is a <u>Precipitation</u> <u>Reaction</u>.
When calcium carbonate reacts with NaCl it produces:
→
Now, calcium chloride is an inorganic compound very soluble in water, so, in this reaction, there are no precipitate and <u>no visible reaction occurs</u>.
When reacts with hydrochloridric acid, the balanced reaction is
→
which, also produces calcium chloride and carbonic acid.
Both are soluble in water but, when carbonic acid is in an "aqueous state", carbonic acid, it dissociates, forming carbon dioxide and water. Therefore, <u>gas is produced and some precipitate dissolves</u>.
In conclusion, sentence B is the correct alternative.