ΔG⁰ = ΔH⁰ - TΔS
ΔH⁰ = Hf,(CH₃OH) - Hf,(CO) = -238.7 + 110.5 = -128.2 kJ/mol
ΔS = S(CH₃OH) - S(CO) - 2S(H₂) = 126.8 - 197.7 - 2 x 130.6 = -332.1 J/mol.K
So
ΔG⁰ = - 128200 + 332.1 T
For the reaction to be spontaneous:
ΔG⁰ < 0
So: -128200 + 332.1 T < 0
332.1 T < 128200
T < 386.028 K
Three complete orders on each side of the m=0 order can be produced in addition to the m = 0 order.
The ruling separation is
d=1 / (470mm −1) = 2.1×10⁻³ mm
Diffraction lines occur at angles θ such that dsinθ=mλ, where λ is the wavelength and m is an integer.
Notice that for a given order, the line associated with a long wavelength is produced at a greater angle than the line associated with a shorter wavelength.
We take λ to be the longest wavelength in the visible spectrum (538nm) and find the greatest integer value of m such that θ is less than 90°.
That is, find the greatest integer value of m for which mλ<d.
since d / λ = 538×10⁻⁹m / 2.1×10 −6 m ≈ 3
that value is m=3.
There are three complete orders on each side of the m=0 order.
The second and third orders overlap.
Learn more about diffraction here : brainly.com/question/16749356
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