Rate law for the given 2nd order reaction is:
Rate = k[a]2
Given data:
rate constant k = 0.150 m-1s-1
initial concentration, [a] = 0.250 M
reaction time, t = 5.00 min = 5.00 min * 60 s/s = 300 s
To determine:
Concentration at time t = 300 s i.e. ![[a]_{t}](https://tex.z-dn.net/?f=%5Ba%5D_%7Bt%7D)
Calculations:
The second order rate equation is:
![1/[a]_{t} = kt +1/[a]](https://tex.z-dn.net/?f=1%2F%5Ba%5D_%7Bt%7D%20%3D%20kt%20%2B1%2F%5Ba%5D)
substituting for k,t and [a] we get:
1/[a]t = 0.150 M-1s-1 * 300 s + 1/[0.250]M
1/[a]t = 49 M-1
[a]t = 1/49 M-1 = 0.0204 M
Hence the concentration of 'a' after t = 5min is 0.020 M
Since obliquity is the angle between the axis of rotation and the direction perpendicular to the orbital plane, it changes as the orbital plane changes due to the influence of other planets. But the axis of rotation can also move (axial precession), due to torque exerted by the sun on a planet's equatorial bulge.
(Got it from google )
2Cu + S = Cu₂S
S⁰ + 2e⁻ = S⁻²
Cu⁰ - 1e⁻ = Cu⁺¹
A sulfur atom gains two electrons.
11. ionic charge +1, helium.
12. ionic charge 2-, neon.
13. ionic charge 3+, neon.