1) For the following molecules: - Draw the Lewis structures/dots - Determine the polarity (polar or non-polar). - List all inter
1 answer:
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The scheme is shown below, the steps involved are as follow,
Step one: Reduction:
The carbonyl group of given compound on reduction using Wolf Kishner reagent converts the carbonyl group into -CH₂- group.
Step two: Epoxidation:
The double bond present in starting compound when treated with m-CPBA (<span>meta-Chloroperoxybenzoic acid) gives corrsponding epoxide.
Step three: Reduction:
The epoxide is reduced to alcohol on treatment with Lithium Aluminium Hydride (LiAlH</span>₄)<span> followed by hydrolysis.
Step four: Oxidation:
The hydroxyl group (alcohol) is oxidized to carbonyl (ketonic group) using oxidizing agent Chromic acid (H</span>₂CrO₄).
Step one: Reduction:
The carbonyl group of given compound on reduction using Wolf Kishner reagent converts the carbonyl group into -CH₂- group.
Step two: Epoxidation:
The double bond present in starting compound when treated with m-CPBA (<span>meta-Chloroperoxybenzoic acid) gives corrsponding epoxide.
Step three: Reduction:
The epoxide is reduced to alcohol on treatment with Lithium Aluminium Hydride (LiAlH</span>₄)<span> followed by hydrolysis.
Step four: Oxidation:
The hydroxyl group (alcohol) is oxidized to carbonyl (ketonic group) using oxidizing agent Chromic acid (H</span>₂CrO₄).
Answer:
Vapour pressure of cyclohexane at 50°C is 490torr
Vapour pressure of benzene at 50°C is 90torr
Explanation:
Using Raoult's law, pressure of a solution is defined by the sum of the product sbetween mole fraction of both solvents and pressure of pure solvents.
In the first solution:
<em>(1)</em>
For the second equation:
<em>(2)</em>
Replacing (2) in (1):
-122.5torr = -0.250P°A
<em>Vapour pressure of cyclohexane at 50°C is 490torr</em>
And for benzene:
<em>Vapour pressure of benzene at 50°C is 90torr</em>