Answer:
water was added to powdered rock
Explanation:
 
        
             
        
        
        
<u>Answer:</u> The standard free energy change of formation of  is 92.094 kJ/mol
 is 92.094 kJ/mol
<u>Explanation:</u>
We are given:

Relation between standard Gibbs free energy and equilibrium constant follows:

where,
 = standard Gibbs free energy = ?
 = standard Gibbs free energy = ?
R = Gas constant = 
T = temperature = ![25^oC=[273+25]K=298K](https://tex.z-dn.net/?f=25%5EoC%3D%5B273%2B25%5DK%3D298K)
K = equilibrium constant or solubility product = 
Putting values in above equation, we get:

For the given chemical equation:

The equation used to calculate Gibbs free change is of a reaction is:  
![\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28product%29%7D%5D-%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28reactant%29%7D%5D)
The equation for the Gibbs free energy change of the above reaction is:
![\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5B%282%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28Ag%5E%2B%28aq.%29%29%7D%29%2B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%7D%29%5D-%5B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28Ag_2S%28s%29%29%7D%29%5D)
We are given:

Putting values in above equation, we get:
![285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol](https://tex.z-dn.net/?f=285.794%3D%5B%282%5Ctimes%2077.1%29%2B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%7D%29%5D-%5B%281%5Ctimes%20%28-39.5%29%29%5D%5C%5C%5C%5C%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%3D92.094J%2Fmol)
Hence, the standard free energy change of formation of  is 92.094 kJ/mol
 is 92.094 kJ/mol
 
        
             
        
        
        
Answer:
-12.5 kJ/mol
Explanation:
The free-energy predicts if a reaction is spontaneous or not. If it is, ΔG < 0. When a reaction happens by steps, the free-energy of the global reaction can be calculated by the sum of the free-energy of the steps (Hess law). If it's needed to operations at the reaction the same operation must be done in the value of ΔG (if the reaction is inverted, the signal of ΔG must be inverted).
 
Phosphocreatine → creatine + Pi ∆G'° = –43.0 kJ/mol 
ATP → ADP + Pi                             ∆G'° = –30.5 kJ/mol (x-1)
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Phosphocreatine → creatine + Pi ∆G'° = –43.0 kJ/mol 
Pi + ADP → ATP                             ∆G'° = 30.5 kJ/mol
 
The bold compounds are in opposite sides, so they'll be canceled in the sum of the reactions:
 
Phosphocreatine + ADP → creatine + ATP
 
∆G'° = -43.0 + 30.5
∆G'° = -12.5 kJ/mol