Answer:
water was added to powdered rock
Explanation:
<u>Answer:</u> The standard free energy change of formation of 
is 92.094 kJ/mol
<u>Explanation:</u>
We are given:
Relation between standard Gibbs free energy and equilibrium constant follows:
where,
= standard Gibbs free energy = ?
R = Gas constant = 
T = temperature = ![25^oC=[273+25]K=298K](https://tex.z-dn.net/?f=25%5EoC%3D%5B273%2B25%5DK%3D298K)
K = equilibrium constant or solubility product = 
Putting values in above equation, we get:
For the given chemical equation:
The equation used to calculate Gibbs free change is of a reaction is:
![\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28product%29%7D%5D-%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28reactant%29%7D%5D)
The equation for the Gibbs free energy change of the above reaction is:
![\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5B%282%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28Ag%5E%2B%28aq.%29%29%7D%29%2B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%7D%29%5D-%5B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28Ag_2S%28s%29%29%7D%29%5D)
We are given:
Putting values in above equation, we get:
![285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol](https://tex.z-dn.net/?f=285.794%3D%5B%282%5Ctimes%2077.1%29%2B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%7D%29%5D-%5B%281%5Ctimes%20%28-39.5%29%29%5D%5C%5C%5C%5C%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%3D92.094J%2Fmol)
Hence, the standard free energy change of formation of is 92.094 kJ/mol
Answer:
-12.5 kJ/mol
Explanation:
The free-energy predicts if a reaction is spontaneous or not. If it is, ΔG < 0. When a reaction happens by steps, the free-energy of the global reaction can be calculated by the sum of the free-energy of the steps (Hess law). If it's needed to operations at the reaction the same operation must be done in the value of ΔG (if the reaction is inverted, the signal of ΔG must be inverted).
Phosphocreatine → creatine + Pi ∆G'° = –43.0 kJ/mol
ATP → ADP + Pi ∆G'° = –30.5 kJ/mol (x-1)
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Phosphocreatine → creatine + Pi ∆G'° = –43.0 kJ/mol
Pi + ADP → ATP ∆G'° = 30.5 kJ/mol
The bold compounds are in opposite sides, so they'll be canceled in the sum of the reactions:
Phosphocreatine + ADP → creatine + ATP
∆G'° = -43.0 + 30.5
∆G'° = -12.5 kJ/mol
