The sign of ΔSsys for a solid explosive converts to a gas is positive.
The term used for the measurement of randomness and disorderliness in a system is known as Entropy (S). ΔS calculates the change in entropy and it is positive when entropy increase and negative when entropy decreases.
Entropy increases when heat is added to the system. Addition of heat increases the randomness of the molecules and hence the entropy increases.
When a solid explosive converts to a gas the randomness increases. Explosive causes heat and the solid is converted into gas. The randomness of molecules is maximum in gases thus the entropy increases. The sign of ΔS is positive for this process.
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Answer:
0.41kg/sec
Explanation:
PV= nRT
Given : V= 505 L
P=0.88 atm
R= 0.08206 Latm/K*mol
T= 172 .0C = 172+273 = 445 K
n = PV /RT = 0.88 * 505 / 0.08206 * 445 = 12.17 moles per sec of N2 are consumed
As per reaction : N2 + 3H2 ----> 2NH3
1 mole N2 is consumed to produce 2 moles NH3
moles of NH3 produced per sec :
(2 moles NH3/1mol N2) * 12.17 moles N2 = 24.34 moles NH3 per sec
grams of NH3 produced per sec =
24.34 moles NH3 per sec * molar mass NH3 = 24.34 moles NH3 per sec * 17.031 g/mol = 414.5 g NH3 per sec
rate in Kg/sec = 414.5 g NH3 per sec * (1kg /1000g) = 0.4145 Kg/sec
= 0.41kg/sec
Grams of Chromium(III) nitrate produced : 268.95 g
<h3>Further explanation</h3>
Given
0.85 moles of Lead(IV) nitrate
Required
grams of Chromium(III) nitrate
Solution
Reaction
Balanced equation :
<em>2Cr₂ + 3Pb(NO₃)₄ ⇒ 4Cr(NO₃)₃ + 3Pb </em>
From the equation, mol ratio of Pb(NO₃)₄ : Cr(NO₃)₃ = 3 : 4, so mol Cr(NO₃)₃
mol Cr(NO₃)₃ =

Mass of Chromium(III) nitrate (MW=238.0108 g/mol) :
mass = mol x MW
mass = 1.13 x 238.0108
mass = 268.95 g
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The electron configuration of Iron is:
[Ar] 3d⁶4s²