Answer:
Reaction 1: Kc increases
Reaction 2: Kc decreases
Reaction 3: The is no change
Explanation:
Let us consider the following reactions:
Reaction 1: A ⇌ 2B ΔH° = 20.0 kJ/mol
Reaction 2: A + B ⇌ C ΔH° = −5.4 kJ/mol
Reaction 3: 2A⇌ B ΔH° = 0.0 kJ/mol
To predict what will happen when the temperature is raised we need to take into account Le Chatelier Principle: when a system at equilibrium suffers a perturbation, it will shift its equilibrium to counteract such perturbation. This means that <em>if the temperature is raised (perturbation), the system will react to lower the temperature.</em>
Reaction 1 is endothermic (ΔH° > 0). If the temperature is raised the system will favor the forward reaction to absorb heat and lower the temperature, thus increasing the value of Kc.
Reaction 2 is exothermic (ΔH° < 0). If the temperature is raised the system will favor the reverse reaction to absorb heat and lower the temperature, thus decreasing the value of Kc.
Reaction 3 is not endothermic nor exothermic (ΔH° = 0) so an increase in the temperature will have no effect on the equilibrium.
Color they look the same hope this helps.
Answer:
a) ΔGrxn = 6.7 kJ/mol
b) K = 0.066
c) PO2 = 0.16 atm
Explanation:
a) The reaction is:
M₂O₃ = 2M + 3/2O₂
The expression for Gibbs energy is:
ΔGrxn = ∑Gproducts - ∑Greactants
Where
M₂O₃ = -6.7 kJ/mol
M = 0
O₂ = 0
b) To calculate the constant we have the following expression:
Where
ΔGrxn = 6.7 kJ/mol = 6700 J/mol
T = 298 K
R = 8.314 J/mol K
c) The equilibrium pressure of O₂ over M is:
Answer:
the electrolysis reaction is a non- spontaneous reaction
Explanation:
Since electrons flow from it, the anode in an electrolytic cell is positive, while the cathode is negative when electrons flow into it. The device functions like a galvanic cell in that direction. In an electrolytic cell, an external voltage is applied and that is what causes a non spontaneous reaction
