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Fittoniya [83]
3 years ago
8

At 25 ∘C only 0.0180 mol of the generic salt AB is soluble (at equilibrium) in 1.00 L of water.What is the value for Ksp for thi

s salt at 25 ∘C?
Chemistry
1 answer:
Ghella [55]3 years ago
6 0

Answer:

Ksp = 3.24 x 10⁻⁴

Explanation:

The dissociation equilibrium for a generic salt AB is:

AB(s) ⇄ A⁺(aq) + B⁻(aq)

              s            s

For instance, the expression for the Ksp constant is:

Ksp = [A⁺] [B⁻] = s x s = s²

According to the problem, 0.0180 mol of the salt is soluble in 1.00 L os water. That means that the solubility of the salt (s) is equal to 0.0180 mol per liter.

s = moles of solute/L of solution = 0.0180 mol/L

Thus, we calculate Ksp from the s value as follows:

Ksp = s² = (0.0180)² = 3.24 x 10⁻⁴

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We are given:

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In 44g of carbon dioxide, 12 g of carbon is contained.

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For calculating the mass of hydrogen:

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So, in 2.505 g of water, =\frac{2}{18}\times 2.505=0.278g of hydrogen will be contained.

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Step 1 : convert given masses into moles.

Moles of C =\frac{\text{ given mass of C}}{\text{ molar mass of C}}= \frac{3.338g}{12g/mole}=0.278moles

Moles of H=\frac{\text{ given mass of H}}{\text{ molar mass of H}}= \frac{0.278g}{1g/mole}=0.278moles

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Step 2 : For the mole ratio, divide each value of moles by the smallest number of moles calculated.

For C =\frac{0.278}{0.104}=3

For H =\frac{0.278}{0.104}=3

For O =\frac{0.104}{0.104}=1

The ratio of C : H : O = 3: 3: 1

Hence the empirical formula is C_3H_3O.

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