The energy that is
essential to break one C-H bond is 414 kJ/mol. Since, there are four C-H bonds
in CH4, the energy Δ HCH4 for
breaking all the bonds is calculated as Δ HCH4 = 4 x bond energy of C-H bond. By
multiplying the 4 with the 414 kJ/mol you can get the answer of 1656 kJ/mol CH4
molecules.
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Answer:
Mostly Para
Explanation:
First, let's assume that the molecule is the toluene (A benzene with a methyl group as radical).
Now the nitration reaction is a reaction in which the nitric acid in presence of sulfuric acid, react with the benzene molecule, to introduce the nitro group into the molecule. The nitro group is a relative strong deactiviting group and is metha director, so, further reactions that occur will be in the metha position.
Now, in this case, the methyl group is a weak activating group in the molecule of benzene, and is always ortho and para director for the simple fact that this molecule (The methyl group) is a donor of electrons instead of atracting group of electrons. Therefore for these two reasons, when the nitration occurs,it will go to the ortho or para position.
Now which position will prefer to go? it's true it can go either ortho or para, however, let's use the steric hindrance principle. Although the methyl group it's not a very voluminous and big molecule, it still exerts a little steric hindrance, and the nitro group would rather go to a position where no molecule is present so it can attach easily. It's like you have two doors that lead to the same place, but in one door you have a kid in the middle and the other door is free to go, you'll rather pass by the door which is free instead of the door with the kid in the middle even though you can pass for that door too. Same thing happens here. Therefore the correct option will be mostly para.
Explanation:
According to the Henderson-Hasselbalch equation, the relation between pH and 
is as follows.
pH = 
where, pH = 7.4 and = 7.21
As here, we can use the nearest to the desired pH.
So, 7.4 = 7.21 + 
0.19 =
= 1.55
1 mM phosphate buffer means ![[HPO_{4}]](https://tex.z-dn.net/?f=%5BHPO_%7B4%7D%5D)
+ ![[H_{2}PO_{4}]](https://tex.z-dn.net/?f=%5BH_%7B2%7DPO_%7B4%7D%5D)
= 1 mM
Therefore, the two equations will be as follows.
= 1.55 ............. (1)
+ = 1 mM ........... (2)
Now, putting the value of from equation (1) into equation (2) as follows.
1.55![[H_{2}PO_{4}] + [tex][H_{2}PO_{4}]](https://tex.z-dn.net/?f=%5BH_%7B2%7DPO_%7B4%7D%5D%20%2B%20%5Btex%5D%5BH_%7B2%7DPO_%7B4%7D%5D)
= 1 mM
2.55 = 1 mM
= 0.392 mM
Putting the value of in equation (1) we get the following.
0.392 mM + = 1 mM
= (1 - 0.392) mM
= 0.608 mM
Thus, we can conclude that concentration of the acid must be 0.608 mM.
Answer:
yes they are same thing by E=MC^2 EINSTEIN'S EQUATION
