The entropy of a system can be calculated by the ratio of the total heat in the system and the temperature. Entropy is a measure used in thermodynamics to approximate the degree of disorder in a system. From the equation for entropy, we can calculate the enthalpy as follows:
S = H / T 109.0 J / mol K = H / 373.15 K H = 40673.35 J / mol
Addition of 6 M HCl would form precipitates of all the three cations, since the chlorides of these cations are insoluble: .
Firstly, the solid produced is partially soluble in hot water. Remember that out of all the three solids, lead(II) choride is the most soluble. It would easily completely dissolve in hot water. This is how we separate it from the remaining precipitate. Therefore, we know that we have lead(II) cations present, as the two remaining chlorides are insoluble even at high temperatures.
Secondly, addition of liquid ammonia would form a precipitate with silver: ; Silver hydroxide at higher temperatures decomposes into black silver oxide: .
Thirdly, we also know we have in the mixture, since addition of potassium chromate produces a yellow precipitate: . The latter precipitate is yellow.
In a redox reaction electrons are lost and gained in equal numbers. The species that is oxidized gives electrons to the species that is reduced. I hope this helps. Let me know if anything is unclear.
The question is incomplete. The complete question is :
In science, we like to develop explanations that we can use to predict the outcome of events and phenomena. Try to develop an explanation that tells how much NaOH needs to be added to a beaker of HCl to cause the color to change. Your explanation can be something like: The color change will occur when [some amount] of NaOH is added because the color change occurs when [some condition]. The goal for your explanation is that it describes the outcome of this example, but can also be used to predict the outcome of other examples of this phenomenon. Here's an example explanation: The color of the solution will change when 40 ml of NaOH is added to a beaker of HCl because the color always changes when 40ml of base is added. Although this explanation works for this example, it probably won't work in examples where the flask contains a different amount of HCl, such as 30ml. Try to make an explanation that accurately predicts the outcome of other versions of this phenomenon.
Solution :
Consider the equation of the reaction between NaOH and
NaOH (aq) + HCl (aq) → NaCl(aq) +
The above equation tells us that of reacts with of .
So at the equivalence point, the moles of NaOH added = moles of present.
If the volume of the taken = mL and the conc. of = mole/L
The volume of NaOH added up to the color change = mole/L
Moles of taken = moles.
The color change will occur when the moles of NaOH added is equal to the moles of taken.
Thus when
or when
or mL of NaOH added, we observe the color change.
Where are the volume and molarity of the taken.
is the molarity of NaOH added.
When both the NaOH and are of the same concentrations, i.e. if , then
Or the 40 mL of will need 40 mL of NaOH for a color change and
30 mL of would need 30 mL of NaOH for the color change (provided the concentration )