Question

List the following compounds in order of increasing reactivity in an SN2 reaction.

Answer 1

Answer:

A- 1-Bromopentane

>2-Bromopentane> 2-Bromo-2-methylbutane

B- 1-Bromo-3-methylbutane>2-Bromo-3-methylbutane> 2-Bromo-2-methylbutane

C- 1-Bromobutane > 1-Bromo-3-methylbutane>1-Bromo-2-methylbutane>1-Bromo-2,2-dimethylpropane

Explanation:

We must bear in mind that the ease of SN2 reaction is methyl > primary> secondary> tertiary.

As a result of this all primary alky halides react faster towards SN2 than secondary and tertiary alkyl halides.

Also, compounds that may form more stable carbocations by 1,2- alkyl shifts are less likely to participate in SN2 reaction