An orbital that penetrates into the region occupied by core electrons is less shielded from nuclear charge than an orbital that does not penetrate and therefore has a lower energy.
Explanation:
The only true statement from the given options is that "an orbital that penetrates into the region occupied by core electrons is less shielded from nuclear charge than an orbital that does not penetrate and therefore has a lower energy." Inner orbitals which are also known to contain core electrons feels the bulk of the nuclear pull on them compared to the outermost orbitals containing the valence electrons.
- The nuclear pull is the effect of the nucleus pulling and attracting the electrons in orbitals.
- This pull is stronger for inner orbitals and weak on the outer ones.
- The outer orbitals are said to be well shielded from the pull of the nuclear charge.
- Also, based on the quantum theory, electrons in the outer orbitals have higher energies because they occupy orbitals at having higher energy value.
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Explanation:
Surface tension is the energy required to increase the surface area of a liquid by a given amount. The stronger the intermolecular interactions, the greater the surface tension. ... The viscosity of a liquid is its resistance to flow. Liquids that have strong intermolecular forces tend to have high viscosities.
The surface tension in plain water is just too strong for bubbles to last for any length of time. ... This separates the water molecules from each other. Since the surface tension forces become smaller as the distance between water molecules increases, the intervening soap molecules decrease the surface tension.
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Kb = [HA} [OH-] / [A-] where [A-] represents the concentration of CN- (.068M)
Kb = Kw / Ka = 1 x10-14 / 4.9 x 10-10 = 2 x 10-5
Since this is a salt solution which could be considered to have formed from the neutralization of a strong base (NaOH) and a weak acid (HCN), the Na+ will have no effect on the pH of the solution while the CN- ion will undergo hydrolysis:
CN- + H2O --> HCN + OH-
Based on this equation, the quantities of HCN and OH- produced must be the same and therefore [HCN]=[OH-]. We will set this equal to x.
Plugging into the original equation yields:
2 x 10-5 = x2 / .068 M
Solving for x yields 1.2 x 10-3 whidh is equal to the [OH-]
The pOH then is equal to -log (1.2x10-3) = 2.9
The pH of the solution would be 14 - 2.9 = 11.1