This is a hypothesis question. This is an educated guess, basically. In my opinion, I think the tails side would hold more water.
Answer:
the answer is decaying wood
Answer:
The pH of 0.1 M BH⁺ClO₄⁻ solution is <u>5.44</u>
Explanation:
Given: The base dissociation constant:
= 1 × 10⁻⁴, Concentration of salt: BH⁺ClO₄⁻ = 0.1 M
Also, water dissociation constant:
= 1 × 10⁻¹⁴
<em><u>The acid dissociation constant </u></em>(
)<em><u> for the weak acid (BH⁺) can be calculated by the equation:</u></em>

<em><u>Now, the acid dissociation reaction for the weak acid (BH⁺) and the initial concentration and concentration at equilibrium is given as:</u></em>
Reaction involved: BH⁺ + H₂O ⇌ B + H₃O+
Initial: 0.1 M x x
Change: -x +x +x
Equilibrium: 0.1 - x x x
<u>The acid dissociation constant: </u>![K_{a} = \frac{\left [B \right ] \left [H_{3}O^{+}\right ]}{\left [BH^{+} \right ]} = \frac{(x)(x)}{(0.1 - x)} = \frac{x^{2}}{0.1 - x}](https://tex.z-dn.net/?f=K_%7Ba%7D%20%3D%20%5Cfrac%7B%5Cleft%20%5BB%20%5Cright%20%5D%20%5Cleft%20%5BH_%7B3%7DO%5E%7B%2B%7D%5Cright%20%5D%7D%7B%5Cleft%20%5BBH%5E%7B%2B%7D%20%5Cright%20%5D%7D%20%3D%20%5Cfrac%7B%28x%29%28x%29%7D%7B%280.1%20-%20x%29%7D%20%3D%20%5Cfrac%7Bx%5E%7B2%7D%7D%7B0.1%20-%20x%7D)





<u>Therefore, the concentration of hydrogen ion: x = 3.6 × 10⁻⁶ M</u>
Now, pH = - ㏒ [H⁺] = - ㏒ (3.6 × 10⁻⁶ M) = 5.44
<u>Therefore, the pH of 0.1 M BH⁺ClO₄⁻ solution is 5.44</u>
Answer:
pKa of the histidine = 9.67
Explanation:
The relation between standard Gibbs energy and equilibrium constant is shown below as:
R is Gas constant having value = 0.008314 kJ / K mol
Given temperature, T = 293 K
Given,
So, Applying in the equation as:-
Thus,
![\frac{[His]}{[His+]}=e^{\frac{15}{-0.008314\times 293}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D%3De%5E%7B%5Cfrac%7B15%7D%7B-0.008314%5Ctimes%20293%7D)
![\frac{[His]}{[His+]}=0.00211](https://tex.z-dn.net/?f=%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D%3D0.00211)
Also, considering:-
![pH=pKa+log\frac{[His]}{[His+]}](https://tex.z-dn.net/?f=pH%3DpKa%2Blog%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D)
Given that:- pH = 7.0
So, 
<u>pKa of the histidine = 9.67</u>