The reaction is:
2 NO₂ (g) + F₂ (g) ⇆ 2 NO₂F (g)
The stoichiometric coefficients of the substances balance out each other to obey the Law of Definite Proportions. Now, you have to note that determining the reaction rate expression is specific to a certain type of reaction. So, this are determined empirically through doing experiments. But in chemical reaction engineering, to make things simple, you assume that the reaction is elementary. This means that the order of a reaction with respect to a certain substance follows their individual stoichiometric coefficients. What I'm saying is, the stoichiometric coefficients are the basis of our reaction rate orders. For this reaction, the rate order is 2 for NO₂, 1 for F₂ and 2 for NO₂F. When the forward and reverse reactions are in equilibrium, then it applies that:
Reaction rate of disappearance of reactants = Reaction rate of formation of products.
Therefore, we can have two reaction rate constants for this. But since the conditions manipulated are the reactant side, let's find the expression for reaction rate of disappearance of reactants.
-r = k[NO₂]²[F₂]
The negative sign before r signifies the rate of disappearance. If it were in terms of the product, that would have been positive. The term k denotes for the reaction rate constant. That is also empirical. As you can notice the stoichiometric coefficients are exponents of the concentrations of the reactants. Let's say initially, there are 1 M of NO₂ and 1 M of F₂. Then,
-r = k(1)²(1)
-r = k
Now, if we change 1 M of NO₂ by increasing it to its half, it would now be 1.5 M NO₂. Then, if we quadruple the concentration of F₂, that would be 4 M F₂. Substituting the values:
-r = k(1.5)²(4)
-r = 9k
So, as you can see the reaction rate increase by a factor of 9.
Answer:
Explanation:
The equation of above line , y = 0.0005x+ 0.458
This can be compared with y = mx+c
Hence slope, m = 0.0005 and Y-intercept, c = 0.458
Or it can be plotted manually where straight line has to be drawn touching maximum number of data points. After drawing a straight linear line, we need to take any two points from the straight line and slope is calculated
Slope,
and y -intercept is calculated using extraplotting backwards such that it touches the Y-axis. the point where straight line touches Y-axis is Y-intercept (c).
Plot the average cell potentials E (y-axis) vs T (x-axis). image attached
Answer:
A fire extinguisher
Explanation:
A lab station usually contains equipment for the people working at the station to use. However, most rooms will only have one fire extinguisher for the whole room meaning it would most likely be located somewhere that is easy to access by all and not just a singular lab station.
~Hope this Helps!~
Explanation:
the stationary phase in TLC is a <u>silica gel coated metal plate or paper</u>.
The<u> individual</u> component of the mixure will travel a greater distance up the plate, resulting in a <u>Rf</u> value for the component.
the <u>p-Xylene spot </u> will travel a greater distance as it is the <u>lighter</u> component
Bromobenzene will travel least as it is the <u>heavier</u> component.
thin layer chromatography (TLC) is a type of chromatographic seperation technique that is based on the molecular size of components. the Rf value is the distance covered by the component relative to that travelled by the solvent which is the mobile phase
