<u>Answer:</u> The volume of balloon at a height of 20 km is 
<u>Explanation:</u>
To calculate the volume when temperature and pressure has changed, we use the equation given by combined gas law. The equation follows:

where,
are the initial pressure, volume and temperature of the gas
are the final pressure, volume and temperature of the gas
We are given:
![P_1=745torr\\V_1=1.41\times 10^4L\\T_1=21^oC=[21+273]K=294K\\P_2=63.1torr\\V_2=?L\\T_2=-40^oC=[-40+273]K=233K](https://tex.z-dn.net/?f=P_1%3D745torr%5C%5CV_1%3D1.41%5Ctimes%2010%5E4L%5C%5CT_1%3D21%5EoC%3D%5B21%2B273%5DK%3D294K%5C%5CP_2%3D63.1torr%5C%5CV_2%3D%3FL%5C%5CT_2%3D-40%5EoC%3D%5B-40%2B273%5DK%3D233K)
Putting values in above equation, we get:

Hence, the volume of balloon at a height of 20 km is 