A hydrate is a substance where in it contains water and other constituent elements. To know whether if that compound was a hydrate,you should record its mass, then put it in a test tube and heat it with a Bunsen burner. If the compound is a hydrate, the water in the compound will discharge in the form of water vapor. At the next 5-10 minutes, remove it in the test tube and weigh it up again. If the mass is now fewer, that means that there was water existing that has now evaporated, and the compound was a hydrate.
When the reaction equation is:
CaSO3(s) → CaO(s) + SO2(g)
we can see that the molar ratio between CaSO3 & SO2 is 1:1 so, we need to find first the moles SO2.
to get the moles of SO2 we are going to use the ideal gas equation:
PV = nRT
when P is the pressure = 1.1 atm
and V is the volume = 14.5 L
n is the moles' number (which we need to calculate)
R ideal gas constant = 0.0821
and T is the temperature in Kelvin = 12.5 + 273 = 285.5 K
so, by substitution:
1.1 * 14.5 L = n * 0.0821 * 285.5
∴ n = 1.1 * 14.5 / (0.0821*285.5)
= 0.68 moles SO2
∴ moles CaSO3 = 0.68 moles
so we can easily get the mass of CaSO3:
when mass = moles * molar mass
and we know that the molar mass of CaSO3= 40 + 32 + 16 * 3 = 120 g/mol
∴ mass = 0.68 moles* 120 g/mol = 81.6 g