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2 years ago

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Calculate the molarity of a solution containing 2.66 moles of KOH in 750 mL of solution?

1 answer:

ASHA 777 [7]2 years ago

6 0

Molarity = moles of solute/volume of solution in liters.

There are 2.66 moles of KOH, the solute, and the volume of the solution is 0.750 L.

The molarity of this solution would thus be (2.66 moles KOH)/(0.750 L) = 3.55 M KOH.

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1. $3.57\times 10^{-4}$ was the $K_a$ value calculated by the student.

2. $5.93\times 10^{-4}$ was the $K_b$ of ethylamine value calculated by the student.

Explanation:

1.

The $pH$ value of Aspirin solution = 2.62

$pH=-\log[H^+]$

$[H^+]=10^{-2.62}=0.00240 M$

Moles of s asprin = $\frac{2.00 g}{180 g/mol}=0.01111 mol$

Volume of the solution = 0.600 L

The initial concentration of Aspirin = c = $\frac{0.01111 mol}{0.600 L}=0.0185 M$

$HAs\rightleftharpoons As^-+H^+$

initially

c 0 0

At equilibrium

(c-x) x x

The expression of dissociation constant :

$K_a=\frac{[As^-][H^+]}{[HAs]}$ :

$K_a=\frac{x\times x }{(c-x)}$

$=\frac{0.00240 M\times 0.00240 M}{(0.0185-0.00240 )}$

$K_a=3.57\times 10^{-4}$

$3.57\times 10^{-4}$ was the $K_a$ value calculated by the student.

2.

The $pH$ value of ethylamine = 11.87

$pH+pOH=14$

$pOH=14-11.87=2.13$

$pOH=-\log[OH^-]$

$[OH^-]=10^{-2.13}=0.00741 M$

The initial concentration of ethylamine = c = 0.100 M

$C_2H_5NH_2+H_2O\rightleftharpoons C_2H_5NH_3^{+}+OH^-$

initially

c 0 0

At equilibrium

(c-x) x x

The expression of dissociation constant :

$K_b=\frac{[C_2H_5NH_3^{+}][OH^-]}{[C_2H_5NH_2]}$ :

$K_b=\frac{x\times x}{(c-x)}$

$=\frac{0.00741\times 0.00741}{(0.100-0.00741)}$

$K_b=5.93\times 10^{-4}$

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