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Sophie [7]
3 years ago
15

According to the Vaporization Heat table, the heat needed for 1 mol of H2O to evaporate at 100°C is 40.7KJ and 44.0KJ/mol is nee

ded to evaporate H2O at 25°C. Thus 44.0-40.7=3.7KJ is the energy needed to heat H2O to 100°C from 25°C.
However, according to the heat capacity of H2O, 3.7KJ will only warm the water by ~+43°C, which is not enough to reach 100°C starting from 25°C!

Am I missing something?!

Chemistry
1 answer:
ASHA 777 [7]3 years ago
6 0

Answer:

Suppose you have a material in it's liquid phase. As you give energy to that liquid, the temperature of the liquid will increase gradually, and the relation between the increase of temperature and the given energy is the specific heat.

Now, there is a point, a critical point, where the temperature stops to increase, which means that we are near a change of phase. So from this point on, the energy is not used to increase the kinetic energy of the particles (which would increase the temperature), the energy is used to break the bonds and allow a change of phase, for example, from liquid to gas.

So, we know that if you have a mol of water at 100°C, then you need to add 40.7 kJ of energy to change the phase of the water from liquid to gas phase.

This means that if you have a mol of water and you give that exact energy, the temperature will not change, instead, you now will have a mol of water at the temperature of 100°C.

Similarly with the case at 25°C (which happens for a particular pressure only)

So the heat of vaporization can not really be related to increases in temperature as you thought.

For changes in temperature, you need to use the specific heat.

We know that for water it is:

c = 4.184 J/g*°C = 76.15 J/mol*°C

So, if you want to increase the temperature from 25° to 100°

This means an increase of 75°C of one mol of water.

We just need to multiply the above number by:

1mol*(75°C)

Energy needed = (76.15 J/mol*°C)*1mol*(75°C) = 5,711.25 J

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Cultural conservation is concerned with how cultural material is preserved as it moves from the past, through the present and into the future. This material may be books in libraries, documents in archives, objects or artwork in museums, or items owned by a community, a family or an individual.

It is the conservator’s job to help ensure the material’s protection and safe passage into the future for as long as is possible.

Art conservation is a complex and highly interdisciplinary task, requiring a knowledge base that may include methods of manufacture, the mechanisms of damage and the cultural significance of an object. Art conservators use history to understand why and when an artwork was made and science to understand how it was made and what has happened to it over time.

When the history of a painting is unclear, conservators will turn to art history to contextualise the work and to science to investigate the evidence of the date and method of manufacture.

Thorough examination and documentation is always the first step in conservation. This involves assessing the original structure and materials of the object, the extent of deterioration, damage and loss, and to ascertain previous restorations or other interventions.

Restoration and preventative conservation

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The terms “conservation” and “restoration” are often used interchangeably, but they represent very different activities.

Restoration seeks to modify the appearance of an object to reduce the visual impact of deterioration or damage and to restore visual continuity. Although conservation may involve restoration, more usually it’s engaged with preventing damage and deterioration.

Preventive conservation brings knowledge of the mechanisms of deterioration to provide the best options for the long-term care of cultural material. Take the example of a newspaper page turning yellow and brittle in the hot summer sun – knowing how the cellulose in the paper ages, that this process involves the creation of acid and that this acid contributes to the discolouration and deterioration of paper, means that appropriate steps can be taken to mitigate this process.

Preventative conservation is a predictive and holistic activity, often involving whole collections.

The operational aspects of air conditioning in museums are often the concern of conservators. Chemical and physical reactions involved in deterioration increase with higher temperatures and with cyclic changes in humidity. As a result, materials may crack or become brittle.

On one hand it makes sense to have continuous and stable air-conditioning; on the other hand, air-conditioning is energy-intensive and expensive to run. Understanding the issues, weighing the risks and advising on the best options for the collection is the job of the conservator.

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Conservation also requires exceptional craftsmanship and art-making skills such as those employed in the original creation of the artwork; being able to replicate the paint layers, carve a section of an object to replace a lost part, or cast a sheet of handmade paper to use as a fill for a large hole are some examples of these kinds of skills.

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