The volume of 0.160 m Li2S solution required to completely react with 130 ml of 0.160 CO(NO3)2 is calculated as below
write the reacting equation
Co(NO3)2 + Li2S = 2LiNO3 + COS
find the moles of CO(NO3)2 = molarity x volume
= 130 ml x 0.160=20.8 moles
since the reacting moles between CO(NO3)2 to LiS is 1:1 the moles of LiS is also 20.8 moles
volume of Lis is therefore = moles of Lis/ molarity of LiS
= 20.8/0.160 = 130 Ml
Answer:
<h3>1)</h3>
Structure One:
Structure Two:
Structure Three:
Structure Number Two would likely be the most stable structure.
<h3>2)</h3>
- All five C atoms: 0
- All six H atoms to C: 0
- N atom: +1.
The N atom is the one that is "likely" to be attracted to an anion. See explanation.
Explanation:
When calculating the formal charge for an atom, the assumption is that electrons in a chemical bond are shared equally between the two bonding atoms. The formula for the formal charge of an atom can be written as:
.
For example, for the N atom in structure one of the first question,
- N is in IUPAC group 15. There are 15 - 10 = 5 valence electrons on N.
- This N atom is connected to only 1 chemical bond.
- There are three pairs, or 6 electrons that aren't in a chemical bond.
The formal charge of this N atom will be
.
Apply this rule to the other atoms. Note that a double bond counts as two bonds while a triple bond counts as three.
<h3>1)</h3>
Structure One:
Structure Two:
Structure Three:
In general, the formal charge on all atoms in a molecule or an ion shall be as close to zero as possible. That rules out Structure number one.
Additionally, if there is a negative charge on one of the atoms, that atom shall preferably be the most electronegative one in the entire molecule. O is more electronegative than N. Structure two will likely be favored over structure three.
<h3>2)</h3>
Similarly,
- All five C atoms: 0
- All six H atoms to C: 0
- N atom: +1.
Assuming that electrons in a chemical bond are shared equally (which is likely not the case,) the nitrogen atom in this molecule will carry a positive charge. By that assumption, it would attract an anion.
Note that in reality this assumption seldom holds. In this ion, the N-H bond is highly polarized such that the partial positive charge is mostly located on the H atom bonded to the N atom. This example shows how the formal charge assumption might give misleading information. However, for the sake of this particular problem, the N atom is the one that is "likely" to be attracted to an anion.
In chemistry and atomic physics, the main group is the group of elements whose lightest members are represented by helium, lithium, beryllium, boron, carbon, nitrogen, oxygen, and fluorine as arranged in the periodic table of the elements
Water has hydrogen bonds between Hydrogen atoms (that are slightly positive in molecules of water ) and Oxygen atoms (that are slightly negative in molecules of water), so it is necessary more energy to break them down and move water molecules from liquid state to gas.
Answer:
B. Ca2+ import into the ER because it has the steeper concentration gradient
Explanation:
ΔGt = RT㏑(C₂/C₁)
where ΔGt is the free energy change for transport; R = 8.315 J/mol; T = 298 K; C₂/C₁ is ratio of concentrations inside and outside each organelle.
For Ca²⁺ import
ΔGt = 8.315 J/mol * 298 K * ㏑(10⁻³/10⁻⁷)
ΔGt= 3.42 kJ/mol
For H⁺ import
ΔGt = 8.315 J/mol * 298 K * ㏑ (10⁻⁴/10⁻⁷)
ΔGt = 2.73 kJ/mol
From the above values, ΔGt is greater for Ca²⁺ import because it has a steeper concentration gradient