Answer:
Natural chemicals are produced by nature without any human intervention. Synthetic chemicals are made by humans using methods different than those nature uses, and these chemical structures may or may not be found in nature. Stay safe .
The rock cycle is referred to as cycle because it repeats over and over again. The definition of cycle is a series of events that are regularly related in the same order. So with the rock cycle they stay in the same order and repeat.
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Ionic compounds are formed between oppositely charged ions.
A binary ionic compound is composed of ions of two different elements - one of which is a positive ion(metal), and the other is negative ion (nonmetal).
To write the empirical formula of binary ionic compound we must remember that one ion should be positive and other ion should be negative, then only the correct formula should be written. To write the empirical formula the charges of opposite ions should be criss-crossed.
First empirical formula of binary ionic compound is written between
First Formula would be 
Second empirical formula is between 
Second Formula would be 
Note : When the subscript are same they get cancel out, so
would be written as 
Third empirical formula is between 
Third Formula would be :
Forth empirical formula is between 
Forth Formula would be :
or 
Note- The subscript will be simplified and the formula will be written as
.
The empirical formula of four binary ionic compounds are : 
I think the answer is D. the upper surface of undergound water.