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The smallest unit of a compound is a molecule, which is made up of atoms held together by bonds.
Fe3N2, also known as Iron (II) nitride, is an ionic compound.
Ionic compounds are compounds that consists of metals and non-metals bonded with ionic bonds. The metal ion gives up electron(s) to the non-metals.
Since iron is a metal and nitrogen is an non-metal, the bond they would form would be an ionic bond. Iron gives up 2 electrons to form iron(II) ion, while nitrogen gains 3 electrons to form nitride ion. Since one iron cannot let a nitrogen gain 3 electrons, so in the compound, there would be 3 iron (ii) ions that has given up 6 electrons in total while 2 nitride ions have gained 6 electrons in total.