Classify the following alcohols as primary secondary and tertiary alcohols?

The equilibrium constant Kp for the reaction (CH3),CCI (g) = (CH3),C=CH, (g) + HCl (g) is 3.45 at 500. K. (5.00 x 10K) Calculate

Karolina [17]

Answer: The value of $K_p$ for the reaction is 6.32 and concentrations of $(CH_3)_2C=CH,HCl\text{ and }(CH_3)_3CCl$ is 0.094 M, 0.094 M and 0.106 M respectively.

Explanation:

Relation of $K_p$ with $K_c$ is given by the formula:

$K_p=K_c(RT)^{\Delta ng}$

where,

$K_p$ = equilibrium constant in terms of partial pressure = 3.45

$K_c$ = equilibrium constant in terms of concentration = ?

R = Gas constant = $0.0821\text{ L atm }mol^{-1}K^{-1}$

T = temperature = 500 K

$\Delta n_g$ = change in number of moles of gas particles = $n_{products}-n_{reactants}=2-1=1$

Putting values in above equation, we get:

$3.45=K_c\times (0.0821\times 500)^{1}\\\\K_c=\frac{3.45}{0.0821\times 500}=0.084$

The equation used to calculate concentration of a solution is:

$\text{Molarity}=\frac{\text{Moles}}{\text{Volume (in L)}}$

Initial moles of $(CH_3)_3CCl(g)$ = 1.00 mol

Volume of the flask = 5.00 L

So, $\text{Concentration of }(CH_3)_3CCl=\frac{1.00mol}{5.00L}=0.2M$

For the given chemical reaction:

$(CH_3)_3CCl(g)\rightarrow (CH_3)_2C=CH(g)+HCl(g)$

Initial: 0.2 - -

At Eqllm: 0.2 - x x x

The expression of $K_c$ for above reaction follows:

$K_c=\frac{[(CH_3)_2C=CH]\times [HCl]}{[(CH_3)_3CCl]}$

Putting values in above equation, we get:

$0.084=\frac{x\times x}{0.2-x}\\\\x^2+0.084x-0.0168=0\\\\x=0.094,-0.178$

Negative value of 'x' is neglected because initial concentration cannot be more than the given concentration

Calculating the concentration of reactants and products:

$[(CH_3)_2C=CH]=x=0.094M$

$[HCl]=x=0.094M$

$[(CH_3)_3CCl]=(0.2-x)=(0.2-0.094)=0.106M$

Hence, the value of $K_p$ for the reaction is 6.32 and concentrations of $(CH_3)_2C=CH,HCl\text{ and }(CH_3)_3CCl$ is 0.094 M, 0.094 M and 0.106 M respectively.

8 0

3 years ago

ObIel WiLll unt COl.. USSMS A certain chemical reaction releases 31.2 kJ/g of heat for each gram of reactant consumed. How can y

aleksandr82 [10.1K]

Answer:

The expression to calculate the mass of the reactant is $m = \frac{1.080kJ}{31.2kJ/g}$

Explanation:

The amount of heat released is equal to the amount of heat released per gram of reactant times the mass of the reactant. To keep to coherence between units we need to transform 1,080 J to kJ. We do so with proportions:

$1,080J.\frac{1kJ}{10^{3}J } =1.080kJ$

Then,

$1.080kJ=31.2\frac{kJ}{g} .m\\m = \frac{1.080kJ}{31.2kJ/g}$

5 0

3 years ago

Read 2 more answers

determine the ph of a buffer that is 0.55 M HNO2 and 0.75 M KNO2. tha value of Ka for HNO2 is 6.8*10^-4

Mariana [72]

Answer:

pH = 3.3

Explanation:

Buffer solutions minimize changes in pH when quantities of acid or base are added into the mix. The typical buffer composition is a weak electrolyte (wk acid or weak base) plus the salt of the weak electrolyte. On addition of acid or base to the buffer solution, the solution chemistry functions to remove the acid or base by reacting with the components of the buffer to shift the equilibrium of the weak electrolyte left or right to remove the excess hydronium ions or hydroxide ions is a way that results in very little change in pH of the system. One should note that buffer solutions do not prevent changes in pH but minimize changes in pH. If enough acid or base is added the buffer chemistry can be destroyed.

In this problem, the weak electrolyte is HNO₂(aq) and the salt is KNO₂(aq). In equation, the buffer solution is 0.55M HNO₂ ⇄ H⁺ + 0.75M KNO₂⁻ . The potassium ion is a spectator ion and does not enter into determination of the pH of the solution. The object is to determine the hydronium ion concentration (H⁺) and apply to the expression pH = -log[H⁺].

Solution using the I.C.E. table:

HNO₂ ⇄ H⁺ + KNO₂⁻

C(i) 0.55M 0M 0.75M

ΔC -x +x +x

C(eq) 0.55M - x x 0.75M + x b/c [HNO₂] / Ka > 100, the x can be

dropped giving ...

≅0.55M x ≅0.75M

Ka = [H⁺][NO₂⁻]/[HNO₂] => [H⁺] = Ka · [HNO₂]/[NO₂⁻]

=> [H⁺] = 6.80x010⁻⁴(0.55) / (0.75) = 4.99 x 10⁻⁴M

pH = -log[H⁺] = -log(4.99 x 10⁻⁴) -(-3.3) = 3.3

Solution using the Henderson-Hasselbalch Equation:

pH = pKa + log[Base]/[Acid] = -log(Ka) + log[Base]/[Acid]

= -log(6.8 x 10⁻⁴) + log[(0.75M)/(0.55M)]

= -(-3.17) + 0.14 = 3.17 + 0.14 = 3.31 ≅ 3.3

3 0

3 years ago

I’ll give brainliest. Help me please

Doss [256]

I picture is unclear but
I can help if u send me it

7 0

3 years ago

For the reaction, 2SO2(g) + O2(g) <--> 2SO3(g), at 450.0 K the equilibrium constant, Kc, has a value of 4.62. A system wa

Nady [450]

Answer:

To the left.

Explanation:

Step 1: Write the balanced reaction at equilibrium

2 SO₂(g) + O₂(g) ⇄ 2 SO₃(g)

Step 2: Calculate the reaction quotient (Qc)

Qc = [SO₃]² / [SO₂]² × [O₂]

Qc = 0.254² / 0.500² × 0.00855

Qc = 30.2

Step 3: Determine in which direction will proceed the system

Since Qc > Kc, the system will shift to the left to attain the equilibrium.

4 0

3 years ago

Classify the following alcohols as primary secondary and tertiary alcohols?​

Classify the following alcohols as primary secondary and tertiary alcohols?