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Montano1993 [528]
3 years ago
12

What is the free energy change if the ratio of the concentrations of the products to the concentrations of the reactants is 22.3

, and the temperature is 37.0 °C? ?G°\' for the reaction is –16.7 kJ/mol.
Chemistry
1 answer:
snow_lady [41]3 years ago
8 0

The free energy change(Gibbs free energy-ΔG)=-8.698 kJ/mol

<h3>Further explanation</h3>

Given

Ratio of the concentrations of the products to the concentrations of the reactants is 22.3

Temperature = 37 C = 310 K

ΔG°=-16.7 kJ/mol

Required

the free energy change

Solution

Ratio of the concentration : equilbrium constant = K = 22.3

We can use Gibbs free energy :

ΔG = ΔG°+ RT ln K

R=8.314 .10⁻³ kJ/mol K

\tt \Delta G=-16.7~kJ/mol+8.314.10^{-3}\times 310\times ln~22.3\\\\\Delta G=-8.698~kJ/mol

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Use bond energies to calculate ΔHrxn Δ H r x n for the reaction. 2H2(g)+O2(g)→2H2O(g) 2 H 2 ( g ) + O 2 ( g ) → 2 H 2 O ( g )
Olenka [21]

Answer:

\large \boxed{\text{-486 kJ}}

Explanation:

You calculate the energy required to break all the bonds in the reactants.

Then you subtract the energy needed to break all the bonds in the products.

                      2H₂   +   O₂ ⟶ 2H-O-H

Bonds:          2H-H    1O=O       4H-O

D/kJ·mol⁻¹:     436      498          464

\begin{array}{rcl}\Delta H & = & \sum{mD_{\text{reactants}}} - \sum{nD_{\text{products}}}\\& = & 2 \times 436 +1 \times 498 - 4 \times 464\\&=& 1370 - 1856\\&=&\textbf{-486 kJ}\\\end{array}\\\text{The enthalpy of reaction is $\large \boxed{\textbf{-486 kJ}}$}.

3 0
2 years ago
What is easier to observe about an object,it’s physical properties or it’s chemical properties. Explain why.
Sladkaya [172]

Answer:

Physical Properties

Explanation:

You are able to see physical properties but are unable to see chemical properties.

7 0
2 years ago
The isomerization of methylisonitrile to acetonitrile (CH3NC(g) ???? CH3CN) is first order in CH3NC. The rate constant for the r
Hoochie [10]

Answer:

The half life is     H_{1/2}= 7333.3sec

Explanation:

   The half life of a first order  reaction is mathematically represented as

                          H_{1/2} = \frac{0.693}{Rate Constant }

 Substituting   9.45 * 10^{-5}s^{-1}  for the rate constant

                         H_{1/2} = \frac{0.693}{9.45*10^{-5}}

                                 H_{1/2}= 7333.3sec

5 0
3 years ago
"How much NH4Cl, when present in 2.00 liters of 0.200 M ammonia, will give a solution with pH = 8.20? For NH3, Kb = 1.8 x 10-5"
Andru [333]

Answer:

245.66g of NH₄Cl is the mass we need to add to obtain the desire pH

Explanation:

The mixture of NH3/NH4Cl produce a buffer. We can find the pH of a buffer using H-H equation:

pH = pKa + log [A⁻] / [HA]

<em>Where [A⁻] is the molar concentration of the base, NH₃, and [HA] molar concentration of the acid, NH₄⁺. This molar concentration can be taken as the moles of each chemical</em>

<em />

First, we need to find pKa of NH₃ using Kb. Then, the moles of NH₃ and finally replace these values in H-H equation to solve moles of NH₄Cl we need to obtain the desire pH.

  • <em>pKa NH₃/NH₄⁺</em>

pKb = - log Kb

pKb = -log 1.8x10⁻⁵ = <em>4.74</em>

pKa = 14 - pKb

pKa = 14 - 4.74

pKa = 9.26

  • <em>Moles NH₃</em>

<em>2.00L ₓ (0.200mol NH₃ / L) = 0.400 moles NH₃</em>

  • <em>H-H equation:</em>

pH = pKa + log [NH₃] / [NH₄Cl]

8.20 = 9.26 + log [0.400 moles] / [NH₄Cl]

-1.06 =  log [0.400 moles] / [NH₄Cl]

0.0087 =  [0.400 moles] / [NH₄Cl]

[NH₄Cl] = 0.400 moles / 0.0087

[NH₄Cl] = 4.59 moles of NH₄Cl we need to add to original solution to obtain a pH of 8.20. In grams (Using molar mass NH₄Cl=53.491g/mol):

4.59 moles NH₄Cl ₓ (53.491g / mol) =

<h3>245.66g of NH₄Cl is the mass we need to add to obtain the desire pH</h3>

<em />

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