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MArishka [77]
4 years ago
6

If 1.87 g‎ of acetic acid (ch3co2h)‎ reacts with 2.31 g‎ of isopentylalcohol (c5h12o)‎ to give‎ 3.20 g of isopentylacetate (c7h1

4o2)‎, what is the percent yield of the reaction?
Chemistry
1 answer:
Orlov [11]4 years ago
8 0

The reaction of acetic acid with isopentyl alcohol is

CH3COOH + C5H12O  ---> C7H14O2  + H2O

Thus one mole of acetic acid reacts with one mole of isopentyl alcohol to give one mole isopentyl acetate

Molar mass of acetic acid = 60.05 g / mole

Moles of acetic acid used = Mass used  / Molar mass = 1.87/ 60.05 = 0.0311

Molar mass of isopentyl alcohol = 88.15 g / mole

Moles of isopentyl alcohol = Mass / Molar mass = 2.31 / 88.15 = 0.0262

Molar mass of isopentyl acetate = 130.19 g / mole

Moles of isopentyl acetate = 3.20 / 130.19 = 0.0246

As per equation 0.0262  should of isopentyl alcohol should react with 0.0262 moles of acetic acid to give 0.0262 isopentyl acetate

Thus theoretical yield = 0.0262 moles

Actual yield = 0.0246

% yield = Actual yield X 100 / theoretical yield = 0.0246 X 100 / 0.0262 = 93.89%

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Explanation:

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• The longest chain of carbons, which consists of the functional group (which is the alkyne group in this case: C≡C).

• There are 8 carbons in the longest chain, so it is called an octane.

2) Now, identify the location of the functional group.

• The location number of the functional group should be as low as possible. Thus although we could count from the right, we start counting from the left since the functional group is closer to the left. From the left, the functional group would be at carbon 8 while from the left, it is on carbon 3.

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3) Lastly, add in the name of the branch.

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• Adding the name of the branch before the parent chain, we would arrive at 7-methyl-3-octyne as the IUPAC name of the alkyne.

Further Explanation:

A) This option is incorrect as there are only 8 carbons in the parent chain. Although there are 9 carbons in total, the 9th carbon is taken care of in '7-methyl'.

B) Location number of the functional group should be as low as possible, so start counting the number of carbons from the left!

C) Since the functional group is an alkyne, the word 'octane' should be 'octyne' instead.

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