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Over [174]
3 years ago
14

Calculate the mass of 120cc of nitrogen at stp .how many numbers of molecules are prrsent

Chemistry
1 answer:
Ratling [72]3 years ago
8 0

Answer:

3.2 x 10²¹molecules

Explanation:

Given parameters:

Volume of nitrogen gas = 120cm³

Unknown:

Mass of nitrogen gas = ?

Number of molecules  = ?

Solution:

To solve this problem, note that;

   1 mole of gas occupies a volume of 22.4L at STP

  Now;

   convert 120cm³ to L ;

           1000cm³  = 1L

           120cm³ gives 0.12L

    Since;

            22.4L of gas has 1 mole at STP

            0.12L of gas will have \frac{0.12}{22.4}   = 0.0054mole at STP

So;

    Mass of N₂  = number of moles x molar mass

 Molar mass of N₂  = 2(14) = 28g/mol

    Mass of N₂  = 0.0054 x 28  = 0.15g

Now;

        1 mole of a gas will have 6.02  x  10²³ molecules

      0.0054 mole of N₂ will contain   0.0054 x  6.02  x  10²³ =

                          3.2 x 10²¹molecules

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Nitrogen (N2) enters a well-insulated diffuser operating at steady state at 0.656 bar, 300 K with a velocity of 282 m/s. The inl
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Answer:

  1. The exit temperature of the Nitrogen would be 331.4 K.
  2. The area at the exit of the diffuser would be 7*10^{-3} m^2.
  3. The rate of entropy production would be 0.

Explanation:

  1. First it is assumed that the diffuser works as a isentropic device. A isentropic device is such that the entropy at the inlet is equal that the entropy T the exit.
  2. It will be used the subscript <em>1 for the</em> <em>inlet conditions of the nitrogen</em>, and the subscript <em>2 for the exit conditions of the nitrogen</em>.
  3. It will be called: <em>v</em> the velocity of the nitrogen stream, <em>T</em> the nitrogen temperature, <em>V</em> the volumetric flow of the specific stream, <em>A</em> the area at the inlet or exit of the diffuser and, <em>P</em> the pressure of the nitrogen flow.
  4. It is known that <em>for a fluid flowing, its volumetric flow is obtain as:</em> V=v*A,
  5. Then for the inlet of the diffuser: V_1=v_1*A_1=282\frac{m}{s}*4.8*10^{-3}m^2=1.35\frac{m^3}{s}
  6. For an ideal gas working in an isentropic process, it follows that: \frac{T_{2} }{T_1}=(\frac{P_2}{P_1})^k where each variable is defined according with what was presented in step 2 and 3, and <em>k </em>is the heat values relationship, 1.4 for nitrogen.
  7. Then <em>solving</em> for T_2, the temperature of the nitrogen at the exit conditions: T_2=T_1(\frac{P_2}{P_1})^k then, T_2=300 K (\frac{0.9 bar}{0.656 bar})^{(\frac{1.4-1}{1.4})}=331.4 K
  8. Also, for an ideal gas working in an isentropic process, it follows that:  \frac{P_2}{P_1}= (\frac{V_1}{V_2})^k, where each variable is defined according with what was presented in step 2 and 3, and <em>k</em> is the heat values relationship, 1.4 for nitrogen.
  9. Then <em>solving</em> for V_2 the volumetric flow at the exit of the diffuser: V_2=V_1*\frac{1}{\sqrt[k]{\frac{P_2}{P_1}}}=\frac{1.35\frac{m^3}{s}}{\sqrt[1.4]{\frac{0.9bar}{0.656bar} }}=1.080\frac{m^3}{s}.
  10. Knowing that V_2=1.080\frac{m^3}{s}, it is possible to calculate the area at the exit of the diffuser, using the relationship presented in step 4, and solving for the required parameter: A_2=\frac{V_2}{v_2}=\frac{1.08\frac{m^3}{s} }{140\frac{m}{s}}=7.71*10^{-3}m^2.
  11. <em>To determine the rate of entropy production in the diffuser,</em> it is required to do a second law balance (entropy balance) in the control volume of the device. This balance is: S_1+S_{gen}-S_2=\Delta S_{system}, where: S_1 and S_2 are the entropy of the stream entering and leaving the control volume respectively, S_{gen} is the rate of entropy production and, \Delta S_{system} is the change of entropy of the system.
  12. If the diffuser is operating at stable state is assumed then \Delta S_{system}=0. Applying the entropy balance and solving the rate of entropy generation: S_{gen}=S_2-S_1.
  13. Finally, it was assume that the process is isentropic, it is: S_1=S_2, then S_{gen}=0.
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Phosphoric acid is a polyprotic acid, with p K values of 2.14, 6.86, and 12.38. Which ionic form predominates at pH 9.3
Vlad1618 [11]

Answer:

HPO₄⁻² predominates at pH 9.3

Explanation:

These are the equilibriums of the phosphoric acid, a tryprotic acid where 3 protons (H⁺) are realesed.

H₃PO₄ + H₂O   ⇄   H₂PO₄⁻   +   H₃O⁺   pKa 2.14

H₂PO₄⁻  +  H₂O   ⇄   HPO₄⁻²  +  H₃O⁺  pKa 6.86

HPO₄⁻²  +  H₂O   ⇄   PO₄⁻³   +   H₃O⁺  pKa 12.38

The H₂PO₄⁻  works as amphoterous, it can be a base and acid, according to these equilibriums.

H₂PO₄⁻ +  H₂O   ⇄   HPO₄⁻²  +  H₃O⁺

H₂PO₄⁻ +  H₂O   ⇄   H₃PO₄  +  OH⁻

pH 9.3 is located between 6.86 and 12.38 where we have this buffer system HPO₄⁻² / PO₄⁻³, where the HPO₄⁻² is another amphoterous:

HPO₄⁻ +  H₂O   ⇄   H₂PO₄⁻  +  OH⁻

HPO₄⁻²  +  H₂O   ⇄   PO₄⁻³   +   H₃O⁺

The media from the two pKa, indicates the pH where the protonated form is in the same quantity as the unpronated form, so:

(6.86 + 12.38) /2 =  9.62

Above this pH, [PO₄⁻³] > [HPO₄⁻²].

In conclussion, at pH 9.3, [HPO₄⁻²] > [PO₄⁻³]

6 0
3 years ago
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