Answer:
Equilibrium constant expression for 
:
![\displaystyle K = \frac{\left(a_{\mathrm{H_2CO_3\, (aq)}}\right)}{\left(a_{\mathrm{H^{+}}}\right)^2\, \left(a_{\mathrm{{CO_3}^{2-}\, (aq)}}\right)} \approx \frac{[\mathrm{H_2CO_3}]}{\left[\mathrm{H^{+}\, (aq)}\right]^{2} \, \left[\mathrm{CO_3}^{2-}\right]}](https://tex.z-dn.net/?f=%5Cdisplaystyle%20K%20%3D%20%5Cfrac%7B%5Cleft%28a_%7B%5Cmathrm%7BH_2CO_3%5C%2C%20%28aq%29%7D%7D%5Cright%29%7D%7B%5Cleft%28a_%7B%5Cmathrm%7BH%5E%7B%2B%7D%7D%7D%5Cright%29%5E2%5C%2C%20%5Cleft%28a_%7B%5Cmathrm%7B%7BCO_3%7D%5E%7B2-%7D%5C%2C%20%28aq%29%7D%7D%5Cright%29%7D%20%5Capprox%20%5Cfrac%7B%5B%5Cmathrm%7BH_2CO_3%7D%5D%7D%7B%5Cleft%5B%5Cmathrm%7BH%5E%7B%2B%7D%5C%2C%20%28aq%29%7D%5Cright%5D%5E%7B2%7D%20%5C%2C%20%5Cleft%5B%5Cmathrm%7BCO_3%7D%5E%7B2-%7D%5Cright%5D%7D)
.
Where
, 
, and 
denote the activities of the three species, and ![[\mathrm{H_2CO_3}]](https://tex.z-dn.net/?f=%5B%5Cmathrm%7BH_2CO_3%7D%5D)
, ![\left[\mathrm{H^{+}}\right]](https://tex.z-dn.net/?f=%5Cleft%5B%5Cmathrm%7BH%5E%7B%2B%7D%7D%5Cright%5D)
, and ![\left[\mathrm{CO_3}^{2-}\right]](https://tex.z-dn.net/?f=%5Cleft%5B%5Cmathrm%7BCO_3%7D%5E%7B2-%7D%5Cright%5D)
denote the concentrations of the three species.
Explanation:
<h3>Equilibrium Constant Expression</h3>
The equilibrium constant expression of a (reversible) reaction takes the form a fraction.
Multiply the activity of each product of this reaction to get the numerator.
is the only product of this reaction. Besides, its coefficient in the balanced reaction is one. Therefore, the numerator would simply be 
.
Similarly, multiply the activity of each reactant of this reaction to obtain the denominator. Note the coefficient "
" on the product side of this reaction. 
is equivalent to 
. The species 
appeared twice among the reactants. Therefore, its activity should also appear twice in the denominator:
.
That's where the exponent "" in this equilibrium constant expression came from.
Combine these two parts to obtain the equilibrium constant expression:
![\displaystyle K = \frac{\left(a_{\mathrm{H_2CO_3\, (aq)}}\right)}{\left(a_{\mathrm{H^{+}}}\right)^2\, \left(a_{\mathrm{{CO_3}^{2-}\, (aq)}}\right)} \quad\begin{matrix}\leftarrow \text{from products} \\[0.5em] \leftarrow \text{from reactants}\end{matrix}](https://tex.z-dn.net/?f=%5Cdisplaystyle%20K%20%3D%20%5Cfrac%7B%5Cleft%28a_%7B%5Cmathrm%7BH_2CO_3%5C%2C%20%28aq%29%7D%7D%5Cright%29%7D%7B%5Cleft%28a_%7B%5Cmathrm%7BH%5E%7B%2B%7D%7D%7D%5Cright%29%5E2%5C%2C%20%5Cleft%28a_%7B%5Cmathrm%7B%7BCO_3%7D%5E%7B2-%7D%5C%2C%20%28aq%29%7D%7D%5Cright%29%7D%20%5Cquad%5Cbegin%7Bmatrix%7D%5Cleftarrow%20%5Ctext%7Bfrom%20products%7D%20%5C%5C%5B0.5em%5D%20%5Cleftarrow%20%5Ctext%7Bfrom%20reactants%7D%5Cend%7Bmatrix%7D)
.
<h3 /><h3>Equilibrium Constant of Concentration</h3>
In dilute solutions, the equilibrium constant expression can be approximated with the concentrations of the aqueous "
" species. Note that all the three species here are indeed aqueous. Hence, this equilibrium constant expression can be approximated as:
![\displaystyle K = \frac{\left(a_{\mathrm{H_2CO_3\, (aq)}}\right)}{\left(a_{\mathrm{H^{+}}}\right)^2\, \left(a_{\mathrm{{CO_3}^{2-}\, (aq)}}\right)} \approx \frac{\left[\mathrm{H_2CO_3\, (aq)}\right]}{\left[\mathrm{H^{+}\, (aq)}\right]^2\cdot \left[\mathrm{{CO_3}^{2-}\, (aq)}\right]}](https://tex.z-dn.net/?f=%5Cdisplaystyle%20K%20%3D%20%5Cfrac%7B%5Cleft%28a_%7B%5Cmathrm%7BH_2CO_3%5C%2C%20%28aq%29%7D%7D%5Cright%29%7D%7B%5Cleft%28a_%7B%5Cmathrm%7BH%5E%7B%2B%7D%7D%7D%5Cright%29%5E2%5C%2C%20%5Cleft%28a_%7B%5Cmathrm%7B%7BCO_3%7D%5E%7B2-%7D%5C%2C%20%28aq%29%7D%7D%5Cright%29%7D%20%5Capprox%20%5Cfrac%7B%5Cleft%5B%5Cmathrm%7BH_2CO_3%5C%2C%20%28aq%29%7D%5Cright%5D%7D%7B%5Cleft%5B%5Cmathrm%7BH%5E%7B%2B%7D%5C%2C%20%28aq%29%7D%5Cright%5D%5E2%5Ccdot%20%5Cleft%5B%5Cmathrm%7B%7BCO_3%7D%5E%7B2-%7D%5C%2C%20%28aq%29%7D%5Cright%5D%7D)
.
Answer:
5.9 × 10^-6.
Explanation:
In the arrangements of crystal solids there is likely going to be an imperfection or defect and one of the defect or imperfections in the arrangements of solids is known as the Schottky defects. The Schottky defects is a kind of lattice arrangements imperfection that occurs when positively charged ions and negatively charged ions leave their position.
So, let us delve right into the solution of the question. We will be making use of the formula below;
Wb/ W = e^ - c/ 2kT.
Where Wb/ W= fraction of lattice sites, c= energy for defect formation = 1.86 eV, and T = temperature= 623° C= 896 k.
So, Wb/ W = e ^ -1.86/ (2 × 896 × 8.62 × 10^ -5).
Wb/ W= 0.000005896557435956372.
Wb/ W=5.9 × 10^-6.
Explanation:
Not only did outermost electron determine the valence electron, but also <em>periodic</em><em> </em><em>table</em><em>.</em><em> </em>whatever group they fall into in periodic table each valence electrons present in a particular atom e.g K and Ca belong to group 1 and 2 respectively and k has 1 and Ca have 2 in each outermost electron
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<h3><u>Answer and explanation</u>;</h3>
The balanced chemical equation will be;
NaHCO3 + CH3COOH = CH3COONa + H2O + CO2
After balancing the chemical equation the number of atoms of each element is the same on the reactants and on the products side.
Sodium atoms - 1
Hydrogen atoms - 5
Carbon atoms - 3
Oxygen atoms - 5
