Answer:
hello,
first one is 25.15
second is 301.55
Explanation:
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Answer: Here's the answer hope this helps
Explanation:
Correct Question:
A chemist measures the enthalpy change ΔH during the following reaction: Fe(s) + 2HCl(g)-->FeCl2(s) + H2 ΔH=-157.0 kJ. Use this information to complete the table below. Round each of your answers to the nearest kJ/mol
Answer:
-314 kJ
+628 kJ
+157 kJ
Explanation:
The enthalpy change of a reaction measures the amount of heat that is lost or gained by it. If ΔH >0 the heat is gained, and the reaction is called endothermic, if ΔH<0, the heat is lost, and the reaction is called exothermic.
If the reaction is inverted, the value of ΔH is inverted too (the opposite endothermic reaction is exothermic), and if the reaction is multiplied by a constant, ΔH will be multiplied by it too.
1) 2Fe(s) + 4HCl --> 2FeCl2(s) + 2H2(g)
This reaction is the product of the given reaction by 2, so
ΔH = 2*(-157) = -314 kJ
2) 4FeCl2(s) + 4H2(g) --> 4Fe(s) + 8HCl(g)
This reaction is the inverted reaction given multiplied by 4, so
ΔH = 4*(157) = +628 kJ
3) FeCl2(s) + H2(g) --> Fe(s) + 2HCl
This reaction is the inverted reaction given, so
ΔH = +157 kJ
First let's find out the oxidation number of Fe in K₄[Fe(CN)₆] compound.
The oxidation number of cation, K is +1. Hence, the total charge of the anion, [Fe(CN)₆] is -4. CN has charge has -1. There are 6 CN in anion. Let's assume the oxidation number of Fe is 'a'.
Sum of the oxidation numbers of each element = Charge of the compound
a + 6 x (-1) = -4
a -6 = -4
a = +2
Hence, oxidation number of Fe in [Fe(CN)₆]⁴⁻ is +2.
Now Fe has the atomic number as 26. Hence, number of electrons in Fe at ground state is 26.
Electron configuration = 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁶ 4s² = [Ar] 3d⁶ 4s²
When making Fe²⁺, Fe releases 2 electrons. Hence, the number of electrons in Fe²⁺ is 26 - 2 = 24.
Hence, the electron configuration of Fe²⁺ = 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁶
= [Ar] 3d⁶
Hence, the number of 3d electrons of Fe in K₄[Fe(CN)₆] compound is 6.