Physical change is easily reversible. Burning/combustion is a chemical process where substances react rapidly with oxygen: this is usually irreversible.
The marshmallow, roasted food and burned wood all undergo combustion and hence are tagged chemical changes.
Prosthesis is used to replace a part of the patient. Some prosthesis powered by external source that allow it to do some degree of movement. Passive prosthesis doesn't have electronic or mechanic part, which makes their function is more to be cosmetic than function.