In balancing equations, we aim to get equal numbers of every type of atom on both sides of the equation, in order to satisfy the law of conservation of mass (which states that in a chemical reaction, every atom in the reactants is reorganised to form products, without exception). Therefore, let me walk you through question a:
<span>_Fe + _ H2SO4 --> _Fe2 (SO4)3 + _H2
First, take a stock-check of exactly what we currently have on each side (assuming that each _ represents a 1):
LHS: Fe = 1, H = 2, S = 1, O = 4
RHS: Fe = 2, H = 2, S = 3, O = 12,
There are two things to note here. Firstly, H2 (it should be subscript in reality) represents two hydrogen atoms bonded together as part of the ionic compound H2SO4 (sulphuric acid) - this two only applies to the symbol which is directly before it. Hence, H2SO4 only contains 1 sulphur atom, because the 2 applies to the hydrogen and the 4 applies to the oxygen. Secondly, the bracket before the 3 (which should also be subscript) means that there is 3 of everything within the bracket - (SO4)3 contains 3 sulphur atoms and 12 oxygen atoms (4 * 3 = 12).
Now let's start balancing. As a prerequisite, you must keep in mind that we can only add numbers in front of whole molecules, whereas it is not scientifically correct to change the little numbers (we could have two sulphuric acids instead of one, represented by 2H2SO4 (where the 2 would be a normal-sized 2 when written down), but we couldn't change H2SO4 to H3SO4).
The iron atoms can be balanced by having two iron atoms on the left-hand side instead of one:
2Fe </span>+ _ H2SO4 --> _Fe2 (SO4)3 + _H2
Now let's balance the sulphur atoms, by multiplying H2SO4 by 3:
2Fe + 3H2SO4 --> _Fe2 (SO4)3 + _H2
This has the added bonus of automatically balancing the oxygens too. This is because SO4- is an ion, which stays the same in a displacement reaction (which this one is). Take another stock check:
LHS: Fe = 2, H = 6, S = 3, O = 12
RHS: Fe = 2, H = 2, S = 3, O = 12
The only mismatch now is in the hydrogen atoms. This is simple to rectify because H2 appears on its own on the right-hand side. Just multiply H2 by 3 to finish off, and fill the third gap with a 1 because it has not been multiplied up. Alternatively, you can omit the 1 entirely:
2Fe + 3H2SO4 --> Fe2 (SO4)3 + 3H2
This is the balanced symbol equation for the displacement of hydrogen with iron in sulphuric acid.
For question b, I will just show you the stages without the explanation (I take the 3 before B2 to be a mistake, because it makes no sense to use 3B2Br6 when B2Br6 balances fine):
<span>B2 Br6 + _ HNO 3 -->_B(NO3)3 +_HBr
B2Br6 + _HNO3 --> _B(NO3)3 + 6HBr
B2Br6 + 6HNO3 --> _B(NO3)3 + 6HBr</span>
<span><span>B2Br6 + 6HNO3 --> 2B(NO3)3 + 6HBr</span>
Hopefully you can get the others now yourself. I hope this helped
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Answer:
closer to F because fluorine has a higher electronegativity than carbon
Explanation:
Electronegativity refers to the ability of an atom in a bonding situation to draw the shared electrons of the bond closer to itself.
Electronegativity increases across the period and decreases down the group. A highly electronegative atom draws the shared electron pair of a bond towards itself.
When two atoms are bonded together, the electron pair is always drawn closer to the atom that has a higher electronegativity.
Hence, the electron pair in a C-F bond could be considered closer to F because fluorine has a higher electronegativity than carbon.
Answer:
C
Explanation: the clumsy definition of the mole obscures its utility. It is nearly analogous to defining a dozen as the mass of a substance that contains the same number of fundamental units as are contained in 733 g of Grade A large eggs. This definition completely obscures the utility of the dozen: that it is 12 things! Similarly, a mole is NA things. The mole is the same kind of unit as the dozen -- a certain number of things. But it differs from the dozen in a couple of ways. First, the number of things in a mole is so huge that we cannot identify with it in the way that we can identify with 12 things. Second, 12 is an important number in the English system of weights and measures, so the definition of a dozen as 12 things makes sense. However, the choice of the unusual number, 6.022 x 1023, as the number of things in a mole seems odd. Why is this number chosen? Would it not make more sense to define a mole as 1.0 x 1023 things, a nice (albeit large) integer that everyone can easily remember? To understand why the particular number, 6.022 x 1023 is used, it is necessary to resurrect an older, in some ways more sensible and useful, definition of the mole, which is grounded in the atomic weight scale addressed above.
The atomic weight scale defines the masses of atoms relative to the mass of an atom of 12C, which is assigned a mass of exactly 12.000 atomic mass units (amu). The number 12 is chosen so that the least massive atom, hydrogen, has a mass of about 1 (actually 1.008) on the scale. The atomic mass unit is a very tiny unit of mass appropriate to the scale of single atoms. Originally, of course, chemists had no idea of its value in laboratory-sized units like the gram. The early versions of the atomic weight scale were established by scientists who had no knowledge of the electron, proton, or neutron. When these were discovered in the late 19th and early 20th centuries, it turned out that the mass of an atom on the atomic weight scale was very nearly the same as the number of protons in its nucleus. This is a very useful correpondence, but it was discovered only after the weight scale had been in use for a long time.
In their desire to be able to count atoms by weighing, chemists gradually developed the concept of the "gram-atomic weight", which was defined in exact correspondence with the atomic weight scale:
1 atom of 12C weighs 12.000 amu
1 gram-atomic weight of 12C weighs 12.000 g
When hydrogen and oxygen combine to form water can be classified as a PRODUCT