The relative volumes of chloroform and water that should be used is 9:10
Concentration of solution in chloroform =
( moles of chloroform )
Concentration of solution in water =
( moles of water )
Dissociation constant at
; 
Concentration of solution in chloroform / Concentration of solution in water
Meaning;

Since
mole is present in chloroform and
mole is present in water, Total mole of Caffeine present is 
Now, we substitute our given values into the equation

Therefore, the relative volumes of chloroform and water that should be used is 9:10
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<span>The filament of the light bulb will get very hot. This will encourage a chemical reaction with most gases that are surrounding that filament - and the result is that the filament burns out. If the filament is in air, it combines with the carbon of carbon dioxide in the air, and the filament disintegrates. But argon is an inert gas - almost nothing reacts with it. So the filament takes a very long time (theoretically infinity) to burn out. But the bulb cannot contain 100% argon: 99.9% is typical; the remaining 0.1% being air. The bulb manufacturers can control the 'life' of a bulb, based on that principle: they do not want their bulbs to last forever!</span>