Answer:
Less
Explanation:
Since [Cu(NH3)4]2+ and [Cu(H2O)6]2+ are Octahedral Complexes the transitions between d-levels explain the majority of the absorbances seen in those chemical compounds. The difference in energy between d-levels is known as ΔOh (ligand-field splitting parameter) and it depends on several factors:
- The nature of the ligand: A spectrochemical series is a list of ligands ordered on ligand strength. With a higher strength the ΔOh will be higher and thus it requires a higher energy light to make the transition.
- The oxidation state of the metal: Higher oxidation states will strength the ΔOh because of the higher electrostatic attraction between the metal and the ligand
A partial spectrochemical series listing of ligands from small Δ to large Δ:
I− < Br− < S2− < Cl− < N3− < F−< NCO− < OH− < C2O42− < H2O < CH3CN < NH3 < NO2− < PPh3 < CN− < CO
Then NH3 makes the ΔOh higher and it requires a higher energy light to make the transition, which means a shorter wavelength.
Density= Mass/Volume I am positive I just had an assignment on this
Answer:
a. 1.23 V
b. No maximum
Explanation:
Required:
a. Is there a minimum standard reduction potential that the half-reaction used at the cathode of this cell can have?
b. Is there a maximum standard reduction potential that the half-reaction used at the cathode of this cell can have?
The standard cell potential (E°cell) is the difference between the standard reduction potential of the cathode and the standard reduction potential of the anode.
E°cell = E°red, cat - E°red, an
If E°cell must be at least 1.10 V (E°cell > 1.10 V),
E°red, cat - E°red, an > 1.10 V
E°red, cat - 0.13V > 1.10 V
E°red, cat > 1.23 V
The minimum standard reduction potential is 1.23 V while there is no maximum standard reduction potential.
