Answer:
React it with CH₃MgBr and work up the product with saturated ammonium chloride solution
Explanation:
Grignard reagents convert esters into tertiary alcohols.
The general equation is
![\text{RCOOR}' \xrightarrow[\text{2. H}^{+}]{\text{1. R$^{\prime \prime}$MgBr}}\text{RR$_{2}^{\prime \prime}$C-OH}](https://tex.z-dn.net/?f=%5Ctext%7BRCOOR%7D%27%20%5Cxrightarrow%5B%5Ctext%7B2.%20H%7D%5E%7B%2B%7D%5D%7B%5Ctext%7B1.%20R%24%5E%7B%5Cprime%20%5Cprime%7D%24MgBr%7D%7D%5Ctext%7BRR%24_%7B2%7D%5E%7B%5Cprime%20%5Cprime%7D%24C-OH%7D)
The Grignard reagent in this synthesis is methylmagnesium bromide. You prepare it by reacting a solution methyl bromide in anhydrous ether with magnesium and a few crystals of iodine.
The reaction consumes 3 mol of CH₃MgBr per mole of dimethyl carbonate, and everything happens in the same pot.
Acid workup of the product usually involves the addition of a saturated aqueous solution of ammonium chloride and extraction with a low-boiling organic solvent.
The mechanism involves:
Step 1. Nucleophilic attack and loss of leaving group
(a) The Grignard reagent attacks the carbonyl of dimethyl carbonate, followed by (b) the loss of a methoxide leaving group.
Step 2. Nucleophilic attack and loss of leaving group
(a) A second mole of the Grignard reagent attacks the carbonyl of methyl acetate, followed by (b) the loss of a methoxide leaving group.
Step 3. Nucleophilic attack and protonation of the adduct.
(a) A third mole of the Grignard reagent attacks the carbonyl of acetone, followed by (b) protonation of the alkoxide to form 2-methylpropan-2-ol.
Sodium sulfate, Na₂SO₄, is a strong electrolyte. It means that it dissociates into 2 Na⁺ ions and 1 SO₄⁻ ion when dissolved in water. So, for every 1 mole of Na₂SO₄, there is an equivalent amount of 2 mol Na⁺ ions. The solution is as follows:
Moles of Na⁺ = (1.27 mol Na₂SO₄/L)*(1 L/1000 mL)*(343 mL)*(2 mol Na⁺/1 mol Na₂SO₄)
<em>Moles of Na⁺ = 0.87 mol</em>
The answer is definitely 4. It has fewer electrons. This is because, whenever the electrons are few, they are positive. Positive electrons are anions, while the negative ones are cations. Hope i helped. Have a nice day.
Answer: Option (c) is the correct answer.
Explanation:
A particle that contains two protons and two neutrons bounded together is known as an alpha particle.
It is known that an alpha particle has a large mass and due to this they travel very slowly. As a result, they tend to have low velocity.
Hence, we can conclude that alpha particles cannot penetrate deeply into solids because they have low velocity.
Hello!
Like many other elements in chemistry, when an atom's valence shell is filled the element becomes stable. Through the octet rule we know that when the very last valence shell becomes filled, the atom is stable and therefore it is highly unlikely for the element to form bonds with that of another.
I hope this helped!
