Answer:
If carbonyl oxygen of 4-hydroxypentanal is enriched with 
, then the oxygen label appears in the water .
Explanation:
- In the first step, -OH group at C-4 gives intramolecular nucleophilic addition reaction at carbonyl center to produce a cyclic hemiacetal.
- Then, one equivalent of methanol gives nucleophilic substitiution reaction by substituting -OH group in cyclic hemiacetal to produce cyclic acetal.
- If carbonyl oxygen of 4-hydroxypentanal is enriched with , then the oxygen label appears in the water produced at the end of reaction.
- Full reaction mechanism has been shown below.
Answer:
8 neutrons
A is the number of neutrons plus protons in the nucleus. However, we already know that there are 7 protons. Therefore, there must be 8 neutrons in the nucleus to add up to 15. Table 3.
Element Symbol Number of Neutrons
carbon 146C 8
nitrogen 147N 7
157N 8
oxygen 168O 8
Explanation:
Answer:
1.0190 x 10⁻⁵ mol
Explanation:
We know the titration required 10.19 mL of 0.001000 M KIO₃, from this information we can calculate the number of moles KIO₃ reacted and from there the number of moles of ascorbic acid since it is a monoprotic acid ( 1 equivalent of ascorbic acid to one equivalent KIO₃).
Molarity = mol/V
V KIO₃ = 10.19 mL = 10.19 mL x 1 L/1000 mL = 0.01019 L
⇒ mol KIO₃ = V x M = 0.01019 L x 0.0010 mol / L = 1.0190 x 10⁻⁵ mol KIO₃
# mol ascorbic acid = # mol KIO₃ = 1.0190 x 10⁻⁵ mol
The surface area is a big help
Answer:
∴ Q = -7.52kCal
Explanation:
Using the formula for specific heat capacity:
Q = mcΔT
where ΔT = change in temperature (final - initial) = (0 - 100)°C = -100°C
m = mass (g) = 75g
c = specific heat capacity = 4.2 J/g°C in water
⇒ Q = 75 × 4.2 × -100
= -31,500J
But 1J - 0.000239kCal
<u>∴ Q = -7.52kCal</u>
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