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emmasim [6.3K]
3 years ago
13

2. Nitric oxide contains 46.66% nitrogen and 53.34% oxygen. Water contains 11.21% hydrogen and 88.79% oxygen. Ammonia contains 1

7.78% hydroger and 82.22% nitrogen. Use these data to verify the law of reciprocal proportions. ​
Chemistry
1 answer:
Mrrafil [7]3 years ago
4 0

Answer:

The law of reciprocal proportions states that if two elements react individually with a given weight of a third element, the ratio of the masses with which they combine with the third element are either the same or a simple multiple of the ratio of the masses with which they combine with each other

The compounds formed includes;

1) Nitric oxide, NO

Nitrogen = 46.66% × 30.01 = 14

Oxygen = 53.34% × 30.01 = 16

2) Water, H₂O

Hydrogen = 11.21% × 18.01528 = 2

Oxygen = 88.79% × 18.01528 ≈ 16

3) Ammonia, NH₃

Hydrogen = 17.78% × 17.031 ≈ 3

Nitrogen = 82.22% × 17.031 ≈ 14

The ratio of nitrogen to oxygen in nitric oxide = 14:16 = 7:8

The ratio of nitrogen to hydrogen in ammonia = 14:3

The ratio in which hydrogen and oxygen combine with nitrogen = 3/16

The ratio of hydrogen and oxygen combine with each other in water = 2/16

Therefore, the ratio with which hydrogen and oxygen combine with nitrogen, is (2/3) times the ratio with which they combine with each other, which verifies the law of reciprocal proportions

Explanation:

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3 years ago
⦁answer Calculate the density in g/L of 478 mL of krypton at 47° C and 671 mm Hg. ⦁ Determine the molar mass of a gas that has a
STALIN [3.7K]

Answer:

The correct answers are:

- Krypton: density= 2.8 g/L

- Molar Mass= 63.99 g/mol

- Mass of O₂= 15.29 g

Explanation:

The general equation of an ideal gas is the folllowing:

P x V = n x R x T

Where: P= pressure (in atm), V= volume; n= number of moles, R= gas constant (0,082 L.atm/K.mol) and T= temperature (in K).

<u>For krypton</u>:

P= 671 mmHg = 0,882 atm

V= 478 ml x 1000 ml/1 L= 0,478 L

T= 47ºC= 320 K

MM= 83.8 g/mol (from Periodic Table, Kr is an inert gas so it is a monoatomic gas)

P x V = n x R x T

Since the number of moles of a compound can be calculated by dividing the mass of compound (m) into its molar mass (MM):

n= m/MM

We can replace the expression in the first equation to obtain:

P x V= \frac{m}{MM} x R x T

m/V= \frac{P x MM}{R x T}

Density (d) is equal to the mass per volume (m/V), so we can directly calculate the density:

d= m/V= \frac{P x MM}{R x T}=

           = (0.882 atm x 83.8 g/mol)/(0.082 L.atm/K.mol x 320 K)

           = 2.81 g/L

<u>For the gas:</u>

d= 2.18 g/L

T= 66ºC= 339 K

P= 720 mmHg= 0.947 atm

d= \frac{P x MM}{R x T}

⇒MM = \frac{dx R x T}{P}

         = (2.18 g/L x 0.082 L.atm/K.mol x 339 K)/(0.947 atm)

         = 63.99 g/mol ≅ 64 g/mol

<u>For the O₂</u>:

V= 5.60 L

P= 1.75 atm

T= 250 K

MM(O₂) = 2 x Atomic Mass O= 2 x 16 g/mol= 32 g/mol

We can use the second equation:

P x V= \frac{m}{MM} x R x T

⇒  m = \frac{P x V x MM}{R x T}= (1.75 atm x 5.6 L x 32 g/mol)/(0.082 L.atm/K.mol x 250 K)

                         = 15.29 g≅ 16 g

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Lithium bromide is a(n) ___________.
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5 0
3 years ago
A tank with volume of 2.4 cu ft is filled with Methane to a pressure of 1500 psia at 104 degrees F. Determine the molecular weig
Soloha48 [4]

Explanation:

It is known that equation for ideal gas is as follows.

               PV = nRT

The given data is as follows.

     Pressure, P = 1500 psia,     Temperature, T = 104^{o}F = 104 + 460 = 564 R

     Volume, V = 2.4 cubic ft,      R = 10.73 psia ft^{3}/lb mol R

Also, we know that number of moles is equal to mass divided by molar mass of the gas.

                n = \frac{mass}{\text{molar mass}}

            m = n \times W

                = 0.594 \times 16.04

                = 9.54 lb

Hence, molecular weight of the gas is 9.54 lb.

  • We will calculate the density as follows.

                d = \frac{PM}{RT}

                    = \frac{1500 \times 16.04}{10.73 \times 564}

                    = 3.975 lb/ft^{3}

  • Now, calculate the specific gravity of the gas as follows.

  Specific gravity relative to air = \frac{\text{density of methane}}{\text{density of air}}

                         = \frac{3.975 lb/ft^{3}}{0.0765 lb/ft^{3}}

                         = 51.96

6 0
3 years ago
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