Answer:
197mL of 0,506M HCl
Explanation:
The reaction of HCl + BaCO₃ is:
BaCO₃(s) + 2HCl → BaCl₂(aq) + CO₂ + H₂O.
The moles of BaCO₃ in 9,85 g are:
9,85 g of BaCO₃ × = <em>0,0499 moles of BaCO₃</em>
As 1 mol of BaCO₃ reacts with two moles of HCl, for a complete reaction of BaCO₃ to dissolve this compound in water you need:
0,0499 moles of BaCO₃ × =<em> 0,0998 moles of HCl</em>
If you have a 0,506M HCl, you need to add:
0,0998 moles of HCl× = 0,197 L ≡ 197mL
I hope it helps!
The mass of ammonium chloride that must be added is : ( A ) 4.7 g
<u>Given data :</u>
Volume of water ( V ) = 250 mL = 0.25 L
pH of solution = 4.85
Kb = 1.8 * 10⁻⁵
Kw = 10⁻¹⁴
Given that the dissolution of NH₄Cl gives NH₄⁺⁺ and Cl⁻ ions the equation is written as :
NH₄CI + H₂O ⇄ NH₃ + H₃O⁺
where conc of H₃O⁺
[ H₃O⁺ ] = and Ka = Kw / Kb
∴ Ka = 5.56 * 10⁻¹⁰
Next step : Determine the concentration of H₃O⁺ in the solution
pH = - log [ H₃O⁺ ] = 4.85
∴ [ H₃O⁺ ] in the solution = 1.14125 * 10⁻⁵
Next step : Determine the concentration of NH₄CI in the solution
C = [ H₃O⁺ ]² / Ka
= ( 1.14125 * 10⁻⁵ )² / 5.56 * 10⁻¹⁰
= 0.359 mol / L
Determine the number of moles of NH₄CI in the solution
n = C . V
= 0.359 mol / L * 0.25 L = 0.08979 mole
Final step : determine the mass of ammonium chloride that must be added to 250 mL
mass = n * molar mass
= 0.08979 * 53.5 g/mol
= 4.80 g ≈ 4.7 grams
Therefore we can conclude that the mass of ammonium chloride that must be added is 4.7 g
Learn more about ammonium chloride : brainly.com/question/13050932
