The answer is the option<span> 3.) Fixing a wineglass requires a large decrease in entropy.
Entropy is a termodynamical variable and it is defined as the degree of disorder of the system.
As per the second law of thermodynamics the spontaneous changes only occur when the entropy increases.
</span>Fixing the broken glasses by itself meant to decrease the entropy spontaneusly which violate the principle or second law of thermodynamics. So, it is not possible.
Answer is: pH of solution is 5,17.
Kb(NH₃) = 1,8·10⁻⁵.
c(NH₄Cl) = 0,084 M = 0,084 mol/L.
Chemical reaction: NH₄⁺ + H₂O → NH₃ + H₃O⁺.
Ka · Kb = 10⁻¹⁴.
Ka(NH₄⁺) = 10⁻¹⁴ ÷ 1,8·10⁻⁵.
Ka(NH₄⁺) = 5,55·10⁻¹⁰.
[H₃O⁺] = [NH₃] = x.
Ka(NH₄⁺) = [H₃O⁺] · [NH₃] ÷ [NH₄⁺].
5,55·10⁻¹⁰ = x² ÷ (0,084 M - x).
Solve quadratic equation: x = [H₃O⁺] = 6,8·10⁻⁶ M.
pH = -log[H₃O⁺].
pH = -log(6,8·10⁻⁶ M) = 5,17.
Answer:
B?
Explanation:
it just makes the most sense in my head