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kogti [31]
3 years ago
13

Deuterium is the isotope of hydrogen of mass number 2, with a proton and a neutron in its nucleus. The chemistry of deuterium is

nearly identical to the chemistry of hydrogen, except that C−D bond is slightly (5.0KJ/mole) stonger than the C−H bond. Reaction rates tend to be slower if a C−D bond as opposed to a C−H bond is broken in a rate limiting step. This effect on the rate is called a kinetic isotope effect.
a. True
b. False
Chemistry
1 answer:
s344n2d4d5 [400]3 years ago
6 0

Answer:

True

Explanation:

We know that the zero-point-energy of a C-D system is quite lower than the zero point energy of the C-H bond so the C-D bond is stronger.

Kinetic isotope effect refers to the change in the rate of reaction owing to a change of one of the atoms of the reactants by replacing it with one of its isotopes.

Since we know that the C-D bond is stronger than the C-H bond, when we replace hydrogen with deuterium in a reaction's rate determining step we experience a little lag in the rate of reaction. This is referred to as the kinetic isotope effect in physical organic chemistry.

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Why would you need a locating agent in an experiment to separate amino acids by chromatography
Nadusha1986 [10]

A locating agent is needed in an experiment to separate amino acids by chromatography as it helps to analyze colorless substances on paper.

<h3>What is chromatography?</h3>

Chromatography is an analytical method frequently used to separate a chemical mixture into its components, allowing for in-depth analysis of each component.

There are many different types of chromatography including liquid, gas, ion-exchange, and affinity chromatography, but they all use the same basic principle.

<h3>What is the use of a locating agent in Chromatography?</h3>

In paper chromatography, colorless compounds are examined using a locating agent.

It is a chemical that combines with colorless substances to produce colorful compounds that are easy to see for analysis. Ninhydrin spray is an example of a locating agent of this type.

Thus, a locating agent is used in an experiment to separate amino acids by chromatography as it helps in determining colorless substances on paper.

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5 0
1 year ago
How many half lives would pass if a mass of copper-66 decayed for 51 minutes? The half life of Cu-66 is 5.10 minutes.
Sveta_85 [38]
Divide 51 by 5.1, it's 10 half lives
4 0
3 years ago
Information collected through our five senses: sight, hearing,
lozanna [386]

Answer:

yes

Explanation:

The five senses: sight, hearing,

taste, smell, and touch can be extended with instruments

5 0
3 years ago
Calculate the H3O+ concentration and then pH in a 0.100 M HC2H3O2 solution that is
Lana71 [14]

Answer:

Please check with the attachment posted.

Please do confirm the answer.

5 0
3 years ago
The rate law for 2NO(g) + O₂(g) → 2NO₂(g) is rate = is rate k[NO]²[O₂]. is rateIn addition to the mechanism in the text (p. 709)
KonstantinChe [14]

The rate law depicts the effect of concentration on reaction rate. Second mechanism 2NO(g) ⇄ N₂O₂(g) [fast], N₂O₂(g) + O₂(g) → 2NO₂(g) [slow] is most reasonable. Thus, option b is correct.

<h3>What is rate law?</h3>

Rate law and equation give the rate at which the reaction takes place under the influence of the concentration of the reactants. The balanced chemical reaction is given as,

2NO(g) + O₂(g) → 2NO₂(g)

The rate of the equation is given as,

rate = k [NO]² [O₂]  

In a multi-step chemical reaction, the slowest step is the rate-determining step. The second mechanism is given as,

2NO (g) → N₂O₂ (g) [fast]

N₂O₂(g) +O₂(g) → 2NO₂ (g) [slow]

Rate is given as,

rate = k [N₂O₂] [O₂]

Therefore, option b. the second mechanism is the most reasonable.

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5 0
1 year ago
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