Answer:
- <u>Decreasing the temperature of the system will shift the reaction rightward.</u>
Explanation:
The complete question is:
Given the equation representing a system at equilibrium:
- N₂(g) + 3H₂(g) ⇌ 2NH₃(g) + energy
what changes occur when the temperature of this system is decreased?
<h2>Solution</h2>
Modifying the temperature of a system in equilibrium changes the equilibrium constant and the equilibrium position (concentrations) of the system.
When the temperature is decreased, following LeChatelier's principle that the system will react in a way that seeks to counteract the disturbance, the reaction will shift toward the reaction that produces more heat energy to compensate the temperature decrease.
Thus, decreasing the temperature of the system will favor the forward reaction, more N₂(g) and H₂(g) will be consumed and more NH₃(g) and energy will be produced. Hence, the equilibrium will shift rightward.
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<u>Answer:</u> The final temperature of the gas is -220.6°C
<u>Explanation:</u>
To calculate the final temperature of the system, we use the equation given by Gay-Lussac Law. This law states that pressure of the gas is directly proportional to the temperature of the gas at constant pressure.
Mathematically,

where,
are the initial pressure and temperature of the gas.
are the final pressure and temperature of the gas.
We are given:
![P_1=6atm\\T_1=-33^oC=[273-33]K=240K\\P_2=1.31atm\\T_2=?](https://tex.z-dn.net/?f=P_1%3D6atm%5C%5CT_1%3D-33%5EoC%3D%5B273-33%5DK%3D240K%5C%5CP_2%3D1.31atm%5C%5CT_2%3D%3F)
Putting values in above equation, we get:

Converting the temperature from kelvins to degree Celsius, by using the conversion factor:


Hence, the final temperature of the gas is -220.6°C