A nuclear family consists of

The vapor pressure of benzene at 298 K is 94.4 mm of Hg. The standard molar Gibbs free energy of formation of liquid benzene at

horsena [70]

Answer:

ΔfG°(C₆H₆(g)) = 129.7kJ/mol

Explanation:

Bringing out the parameters mentioned in the question;

Vapor pressure = 94.4 mm of Hg

The vaporization reaction is given as;

C₆H₆(l) ⇄ C₆H₆(g)

Equilibrium in terms of activities is given by:

K = a(C₆H₆(g)) / a(C₆H₆(l))

Activity of pure substances is one:

a(C₆H₆(l)) = 1

Assuming ideal gas phase activity equals partial pressure divided by total pressure. At standard conditions

K = p(C₆H₆(g)) / p°

Where p° = 1atm = 760mmHg standard pressure

We now have;

K = 94mmHg / 760mmHg = 0.12421

Gibbs free energy is given as;

ΔG = - R·T·ln(K)

where R = gas constant = 8.314472J/molK

So ΔG° of vaporization of benzene is:

ΔvG° = - 8.314472 · 298.15 · ln(0.12421)

ΔvG° = 5171J/mol = 5.2kJ/mol

Gibbs free energy change of reaction = Gibbs free energy of formation of products - Gibbs free energy of formation of reactants:

ΔvG° = ΔfG°(C₆H₆(g)) - ΔfG°(C₆H₆(l))

Hence:

ΔfG°(C₆H₆(g)) = ΔvG°+ ΔfG°(C₆H₆(l))

ΔfG°(C₆H₆(g)) = 5.2kJ/mol + 124.5kJ/mol

ΔfG°(C₆H₆(g)) = 129.7kJ/mol

6 0

4 years ago

I set up the conversion factor as 1 mol H20 / 18.02 g H2O because?

Andrej [43]

Answer:

How many grams of H2O are in 1.0 mole of H2O?

18.02 grams

The average mass of one H2O molecule is 18.02 amu. The number of atoms is an exact number, the number of mole is an exact number; they do not affect the number of significant figures. The average mass of one mole of H2O is 18.02 grams.

#Yourchuu

8 0

3 years ago

Many chemical names are similar at ﬁrst glance. Give the formulas of the species in each set: (a) ammonium ion and ammonia; (b)

ohaa [14]

Answer:

a) Ammonium ion: NH₄⁺, ammonia: NH₃.

b)Magnesium sulfide: MgS, magnesium sulfite: MgSO₃, magnesium sulfate: MgSO₄.

c) Chloric acid: HClO₃, chlorous acid HClO₂.

d) Cupric bromide: CuBr₂, cuprous bromide: CuBr.

Explanation:

a) Ammonia is the neutral substance, which as molecular formula NH₃ when it gains a proton, it becomes the ammonium ion NH₄⁺.

b) In the name of salts, first, it comes the cation name, in this case, all the cations are the magnesium (Mg²⁺). The ions of sulfur can be oxidized or not, the termination "ide" indicates the non-oxidized ion (S⁻²), "ite" the less oxidized (SO₃⁻²), and "ate" the more oxidized (SO₄⁻²). To do the molecular formula, the charges are replaced without the signals and put down. If they are equal, the number is not put.

Magnesium sulfide: MgS

Magnesium sulfite: MgSO₃

Magnesium sulfate: MgSO₄

c) The acids can be oxidized or not, when it has no oxygens, the name is given "hydro" + the anion name, as hydrochloric acid (HCl). When there's oxygen in the molecule, the more oxidized is name as "'per" + anion name + "ic", the second more oxidized as anion name + "ic", the second less oxidized as anion name + "us", and the less oxidized as "hypo" + anion name + "us". In this case:

chloric acid: HClO₃

chlorous acid HClO₂

d) The salts of copper are named depends on the oxidation number of the cupper. The one with a higher oxidation number( +2) is called cupric, and the other (+1), cuprous. Thus:

cupric bromide: CuBr₂ (oxidation number = +2)

cuprous bromide: CuBr (oxidation number = +1)

5 0

3 years ago

Read 2 more answers

You are practicing classification by sorting pictures into groups based on the characteristics of the kingdoms. While you are so

posledela

Answer: D

Explanation: fungi kingdom is Hetrotropiv and is unicellular

7 0

3 years ago

The oxidation of Cu₂O(s) to CuO(s) is an exothermic process:

Alex73 [517]

Answer:

w = 7376.6 J

Explanation:

To calculate the work done in the system, we need first to calculate the number of moles of all compounds.

The following expression, that comes from the 1° law of thermodynamic, will help you to get the work:

w = ΔnRT

Where:

Δn: difference in the number of moles between products and reactants

R: constant universal of gases (8.314 J / mol K)

T: Temperature in Kelvin.

As we are doing this reaction in STP, then the Pressure is 1 atm, and temperature is 0 °C or 273 K.

Now, we already have the moles of Cu₂O, let's see, according to the balanced reaction, how many moles we should have of O₂ and CuO.

If 1 mole of O₂ reacts with 2 moles of Cu₂O then 6.5 moles of Cu₂O will be:

moles O₂ = 6.5 moles Cu₂O * (1 mole O₂/2 moles Cu₂O) = 3.25 moles O₂

If 2 moles of Cu₂O produces 4 moles of CuO, then 6.5 moles will be:

moles CuO = 6.5 moles Cu₂O*(4 moles CuO/2 moles Cu₂O) = 13 moles CuO

Now that we have the moles, let's calculate the value of Δn.

Δn = moles product - moles reactants

Δn = 13 - (6.5 + 3.25) = 3.25 moles

Now, we can calculate the work done in the system:

w = 3.25 * (8.314 * 273)

Hope this helps

8 0

3 years ago