Given buffer:
potassium hydrogen tartrate/dipotassium tartrate (KHC4H4O6/K2C4H4O6 )
[KHC4H4O6] = 0.0451 M
[K2C4H4O6] = 0.028 M
Ka1 = 9.2 *10^-4
Ka2 = 4.31*10^-5
Based on Henderson-Hasselbalch equation;
pH = pKa + log [conjugate base]/[acid]
where pka = -logKa
In this case we will use the ka corresponding to the deprotonation of the second proton i.e. ka2
pH = -log Ka2 + log [K2C4H4O6]/[KHC4H4O6]
= -log (4.31*10^-5) + log [0.0451]/[0.028]
pH = 4.15
V1 = 445ml V2 = 499ml
T1 = 274 K T2 = ?
By Charles Law,
V1/T1 = V2/T2
445/274 = 499/T2
By solving we get,
T2 = 307.25 K
Answer: Since this is merely a Physical Change, it is improper to write it as a chemical equation.
No because 2 pounds only equals 16 ounces times 2 so it equals 32 ounces which is not bigger than 80