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Suppose you have just added 100 ml of a solution containing 0.5 mol of acetic acid per liter to 400 ml of 0.5 m naoh. what is th

Tpy6a [65]

$pH = 13.5$

Explanation:

Sodium hydroxide completely ionizes in water to produce sodium ions and hydroxide ions. Hydroxide ions are in excess and neutralize all acetic acid added by the following ionic equation:

$\text{HAc} + \text{OH}^{-} \to \text{Ac}^{-} + \text{H}_2\text{O}$

The mixture would contain

$0.4 \times 0.5 - 0.1 \times 0.5 = 0.15 \; \text{mol}$ of $\text{OH}^{-}$ and
$0.1 \times 0.5 = 0.05 \; \text{mol}$ of $\text{Ac}^{-}$

if $\text{Ac}^{-}$ undergoes no hydrolysis; the solution is of volume $0.1 + 0.4 = 0.5 \; \text{L}$ after the mixing. The two species would thus be of concentration $0.30 \; \text{mol} \cdot \text{L}^{-1}$ and $0.10 \; \text{mol} \cdot \text{L}^{-1}$ , respectively.

Construct a RICE table for the hydrolysis of $\text{Ac}^{-}$ under a basic aqueous environment (with a negligible hydronium concentration.)

$\begin{array}{cccccccc} \text{R} & \text{Ac}^{-}(aq) &+ & \text{H}_2\text{O}(aq) & \leftrightharpoons & \text{HAc}(aq) & + & \text{OH}^{-} (aq)\\ \text{I} & 0.10 \; \text{M} & & & & & &0.30 \; \text{M}\\ \text{C} & -x \; \text{M}& & & & +x \; \text{M}& & +x \; \text{M} \\ \text{E} & (0.10 - x) \; \text{M} & & & & x \; \text{M} & & (0.30 +x) \; \text{M} \end{array}$

The question supplied the <em>acid</em> dissociation constant $pK_a$ for acetic acid $\text{HAc}$ ; however, calculating the hydrolysis equilibrium taking place in this basic mixture requires the <em>base</em> dissociation constant $pK_b$ for its conjugate base, $\text{Ac}^{-}$ . The following relationship relates the two quantities:

$pK_{b} (\text{Ac}^{-}) = pK_{w} - pK_{a}( \text{HAc})$

... where the water self-ionization constant $pK_w \approx 14$ under standard conditions. Thus $pK_{b} (\text{Ac}^{-}) = 14 - 4.7 = 9.3$ . By the definition of $pK_b$ :

$[\text{HAc} (aq)] \cdot [\text{OH}^{-} (aq)] / [\text{Ac}^{-} (aq) ] = K_b = 10^{-pK_{b}}$

$x \cdot (0.3 + x) / (0.1 - x) = 10^{-9.3}$

$x = 1.67 \times 10^{-10} \; \text{M} \approx 0 \; \text{M}$

$[\text{OH}^{-}] = 0.30 +x \approx 0.30 \; \text{M}$

$pH = pK_{w} - pOH = 14 + \text{log}_{10}[\text{OH}^{-}] = 14 + \text{log}_{10}{0.30} = 13.5$

6 0

3 years ago

A freighter ship carrying a cargo of uranium hexafluoride sank in the English Channel in late August 1984. The cargo of uranium

DiKsa [7]

Answer:

Heyo (Ish Mash Potato) XD

Explanation:

a freighter carrying a cargo of uranium hexafluoride sank in the english channel in 1984. the cargo of uranium hexafluoride weighed 2.25x10 to the eight power. kg and was contained in 30 drums, each having a volume of 1.62x10 to the sixth power L. what is the density in g/ml, of uranium hexafloride.

Hope Mr. Mash Potato Helped!!!

3 0

3 years ago

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Benzene is the compound name and it is a covalent compound

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