A) Compare the masses of the three cylinders. (1 point)

The reaction 2NO(g)+O2(g)−→−2NO2(g) is second order in NO and first order in O2. When [NO]=0.040M, and [O2]=0.035M, the observed

Oksanka [162]

Answer:

(a) The rate of disappearance of $O_{2}$ is: $4.65*10^{-5}$ M/s

(b) The value of rate constant is: 0.83036 $M^{-2}s^{-1}$

(c) The units of rate constant is: $M^{-2}s^{-1}$

(d) The rate will increase by a factor of 3.24

Explanation:

The rate of a reaction can be expressed in terms of the concentrations of the reactants and products in accordance with the balanced equation.

For the given reaction:

$2NO(g)+O_{2}->2NO_{2}$

rate = $-\frac{1}{2} \frac{d}{dt}[NO]$ = $-\frac{d}{dt}[O_{2}]$ = $\frac{1}{2}\frac{d}{dt}[NO_{2}]$ -----(1)

According to the question, the reaction is second order in NO and first order in $O_{2}$ .

Then we can say that, rate = k $[NO]^{2}[O_{2}]$ -----(2)

where k is the rate constant.

The rate of disappearance of NO is given:

$-\frac{d}{dt}[NO]$ = $9.3*10^{-5}$ M/s.

(a) From (1), we can get the rate of disappearance of $O_{2}$ .

Rate of disappearance of $O_{2}$ = $-\frac{d}{dt}[O_{2}]$ = (0.5)*( $9.3*10^{-5}$ ) M/s = $4.65*10^{-5}$ M/s.

(b) The rate of the reaction can be obtained from (1).

rate = $-\frac{1}{2} \frac{d}{dt}[NO]$ = (0.5)*( $9.3*10^{-5}$ )

rate = $4.65*10^{-5}$ M/s

The value of rate constant can be obtained by using (2).

rate constant = k = $\frac{rate}{[NO]^{2}[O_{2}]}$

k = $\frac{4.65*10^{-5}}{(0.040)^{2}(0.035)}$ = 0.83036 $M^{-2}s^{-1}$

(c) The units of the rate constant can be obtained from (2).

k = $\frac{rate}{[NO]^{2}[O_{2}]}$

Substituting the units of rate as M/s and concentrations as M, we get:

$\frac{Ms^{-1} }{M^{3}}$ = $M^{-2}s^{-1}$

(d) The reaction is second order in NO. Rate is proportional to square of the concentration of NO.

$rate\alpha [NO]^{2}$

If the concentration of NO increases by a factor of 1.8, the rate will increase by a factor of $(1.8)^{2}$ = 3.24

5 0

3 years ago

In the equilibrium constant expression for the reaction below what is the correct exponent for N2O4?

irga5000 [103]

As we have the balanced reaction equation is:

N2O4 (g) ↔ 2NO2(g)

from this balanced equation, we can get the equilibrium constant expression

KC = [NO2]^2[N2O4]^1

from this expression, we can see that [NO2 ] is with 2 exponent of the stoichiometric and we can see that from the balanced equation as NO2
is 2NO2 in the balanced equation.

and [N2O4] is with 1 exponent of the stoichiometric and we can see that from the balanced equation as N2O4 is 1 N2O4 in the balanced equation.

∴ the correct exponent for N2O4 in the equilibrium constant expression is 1

7 0

4 years ago

What is the function of a hypothesis in the scientific inquiry process?

LuckyWell [14K]

It's a question that scientists can test.

3 0

3 years ago

Please help me

Wittaler [7]

Answer:

pH = 6.999

The solution is acidic.

Explanation:

HBr is a strong acid, a very strong one.

In water, this acid is totally dissociated.

HBr + H₂O → H₃O⁺ + Br⁻

We can think pH, as - log 7.75×10⁻¹² but this is 11.1

acid pH can't never be higher than 7.

We apply the charge balance:

[H⁺] = [Br⁻] + [OH⁻]

All the protons come from the bromide and the OH⁻ that come from water.

We can also think [OH⁻] = Kw / [H⁺] so:

[H⁺] = [Br⁻] + Kw / [H⁺]

Now, our unknown is [H⁺]

[H⁺] = 7.75×10⁻¹² + 1×10⁻¹⁴ / [H⁺]

[H⁺] = (7.75×10⁻¹² [H⁺] + 1×10⁻¹⁴) / [H⁺]

This is quadratic equation: [H⁺]² - 7.75×10⁻¹² [H⁺] - 1×10⁻¹⁴

a = 1 ; b = - 7.75×10⁻¹² ; c = -1×10⁻¹⁴

(-b +- √(b² - 4ac) / (2a)

[H⁺] = 1.000038751×10⁻⁷

- log [H⁺] = pH → 6.999

A very strong acid as HBr, in this case, it is so diluted that its pH is almost neutral.

8 0

3 years ago

A sucrose solution is prepared to a final concentration of 0.250 M . Convert this value into terms of g/L, molality, and mass %.

MArishka [77]

Answer:

A. 85.6 g

= 0.0856 kg.

B. 0.00027 mol/g

= 0.27 mol/kg.

C. 8.39 %

Explanation:

Given:

Molar concentration = 0.25 M

Molar weight of sucrose = 342.296 g/mol

Density of solution = 1.02 g/mL

Mass of water = 934.4 g.

Density in g/l = 1.020 g/ml * 1000ml/1 l

= 1020 g/l

Mass of solution in 1 l of solution = 1020 g

Mass of solution = mass of solvent + mass of solute

Mass of sucrose = 1020 - 934.4

= 85.6 g of sucrose in 1 l of solution.

A.

Density of sucrose = mass/volume

= molar mass/molar concentration

= 342.296 * 0.25

= 85.6 g/l

Number of moles = mass/molar mass

= 85.6/342.296

= 0.25 mol

B.

Molality = number of moles of solute/mass of solvent

= 0.25/934.4

= 0.00027 mol/g

C.

% mass of sucrose = mass of sucrose/total mass of solution * 100

= 85.6/1020 * 100

= 8.39 %

6 0

3 years ago