Answer: Linear
Explaination: The central atom of a carbon dioxide molecule is carbon. Carbon is tetravalent which just means it has 4 valence electrons. Because the valence shell isn’t full, the carbon atom can bond with other atoms creating a total of 4 bonds. This then allows the carbon to double bond with 2 oxygen atoms. Now, the atoms in the CO2 molecule Don’t share the electrons evenly because of atomic number or proton count. Because oxygen has an atomic number of 6, carbon has an atomic number of 4, and opposites attract (referring to the positivity of the nucleus and the negativity of the shared electrons), the oxygen atoms will have a slightly negative charge (-) and the oxygen will have a slightly positive charge (+ ). Therefore, the slightly negative oxygen atoms repel creating that linear shape.
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Answer : The final temperature of the solution in the calorimeter is, 
Explanation :
First we have to calculate the heat produced.

where,
= enthalpy change = -44.5 kJ/mol
q = heat released = ?
m = mass of
= 1.52 g
Molar mass of
= 40 g/mol

Now put all the given values in the above formula, we get:


Now we have to calculate the final temperature of solution in the calorimeter.

where,
q = heat produced = 1.691 kJ = 1691 J
m = mass of solution = 1.52 + 35.5 = 37.02 g
c = specific heat capacity of water = 
= initial temperature = 
= final temperature = ?
Now put all the given values in the above formula, we get:


Thus, the final temperature of the solution in the calorimeter is, 