Answer:
S = 0.788 g/L
Explanation:
The solubility product (Kps) is an equilibrium solubization constant, which can be calculated by the equation:
![Kps = \frac{[product]^x}{[reagent]^y}](https://tex.z-dn.net/?f=Kps%20%3D%20%5Cfrac%7B%5Bproduct%5D%5Ex%7D%7B%5Breagent%5D%5Ey%7D)
Where x and y are the stoichiometric coefficients of the product and the reagent, respectively. Because of the aggregation form, the concentration of solids is always equal to 1 for use in this equation.
Analyzing the equation, we see that for 1 mol of
is necessary 2 mols of
, so if we call "x" the molar concentration of
, for
we will have 2x, so:
![Kps = [Fe^{+2}].[F^-]^2\\\\2.36x10^{-6} = x(2x)^2\\\\2.36x10^{-6} = 4x^3\\\\x^3 = 5.9x10^{-7}\\\\x = \sqrt[3]{5.9x10^{-7}} \\\\x = 8.4x10^{-3} mol/L](https://tex.z-dn.net/?f=Kps%20%3D%20%5BFe%5E%7B%2B2%7D%5D.%5BF%5E-%5D%5E2%5C%5C%5C%5C2.36x10%5E%7B-6%7D%20%3D%20x%282x%29%5E2%5C%5C%5C%5C2.36x10%5E%7B-6%7D%20%3D%204x%5E3%5C%5C%5C%5Cx%5E3%20%3D%205.9x10%5E%7B-7%7D%5C%5C%5C%5Cx%20%3D%20%5Csqrt%5B3%5D%7B5.9x10%5E%7B-7%7D%7D%20%5C%5C%5C%5Cx%20%3D%208.4x10%5E%7B-3%7D%20mol%2FL)
So, to calculate the solubility (S) of FeF2, which is in g/L, we multiply this concentration by the molar mass of FeF2, which is:
Fe = 55.8 g/mol
F = 19 g/mol
FeF2 = Fe + 2xF = 55.8 + 2x19 = 93.8 g/mol
So,
[tex]S = 8.4x10^{-3}x93.8
S = 0.788 g/L
During a phase change the temperature does not change since all of the heat is being absorbed in order to break the intermolecular forces. Due to that, the formula will not need to have T in it and is actually q=nΔH(v).
n=the number of moles (in this case 2.778mol of water since you divide 50g by 18g/mol).
ΔH(v)=the molar heat of vaporization (in this case 40.7kJ/mol).
q=the heat that must be absorbed
q=2.778mol×40.7kJ/mol
q=113.1kJ
Therefore the water needs to absorb 1.13×10²kJ.
I hope this helps. Let me know if anything is unclear.
The answer is
C. A single replacement reaction (acid reactions)
An example would be the reaction between simple metal Potassium (K) and Water (H2O), resulting in a much solid compound called Potassium Hydroxide (KOH) and hydrogen gas is set free.
K+H2O --> KOH
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The solution would be like this for this specific problem:
<span>Given:
H2 = </span><span>2.6 atm
CL2 = 3.14 atm</span>
<span>
pressure H2 = 2.6 - x
pressure Cl2 = 3.14 - x
<span>pressure HBr = 2x = 1.13
x = 1.13 / 2 = 0.565
<span>pressure H2 = 2.6 - 0.565 = 2.035
pressure Br2 = 3.14 - 0.565 = 2.575
Kp = (1.13)^2 / 2.035 x 2.575</span></span></span>
= 1.2769 / (5.240125)
= 0.24367739319195629875241525726963
= 0.244
<span>Therefore, the Kp for the reaction at the given temperature
is 0.244.
To add, </span>the hypothetical pressure of a gas if
it alone occupied the whole volume of the original mixture at the same
temperature is called the partial pressure or Kp.