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iragen [17]
3 years ago
9

When N,N-Dimethylaniline is treated with bromine, ortho and para products are observed. However, when N,N-Dimethylaniline is tre

ated with a mixture of nitric and sulfuric acid, only the meta product is observed. Explain these results. (Hint: what can happen to the nitrogen atom in the presence of the strong acids
Chemistry
1 answer:
lilavasa [31]3 years ago
6 0

Answer:

See explanation below

Explanation:

To get a better understanding watch the picture attached.

In the case of the reaction with Bromine, the -N(CH₃)₂ is a strong ring activator, therefore, it promotes a electrophilic aromatic sustitution, so, in the mechanism of reaction, the lone pair of the Nitrogen, will move to the ring by resonance and activate the ortho and para positions. That's why the bromine wil go to the ortho and para positions, mostly the para position, because the -N(CH₃)₂ cause a steric hindrance in the ortho position.

In the case of the reaction with HNO₃/H₂SO₄, the acid transform the -N(CH₃)₂ in a protonated form, the anilinium ion, which is a deactivating of the ring, and also a strong electron withdrawing, so, the electrophile will go to the meta position instead.

Hope this helps.

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A blacksmith heated an iron bar to 1445 °C. The blacksmith then tempered the metal by dropping it into 42,800 mL of
Wittaler [7]

Answer:

6626 g

Explanation:

Given that:

Density of water = 1.00 g/ml, volume of water = 42800 ml.

Since density = mass/ volume

mass of water = volume of water * density of water = 42800 ml * 1 g/ml = 42800 g

Initial temperature of water = 22°C and final temperature of water = 45°C.

specific heat capacity for water = 4.184 J/g°C

ΔT water = 45 - 22 = 23°C

For iron:

mass = m,  

specific heat capacity for iron  = 0.444 J/g°C

Initial temperature of iron = 1445°C and final temperature of water = 45°C.

ΔT iron = 45 - 1445 = -1400°C

Quantity of heat (Q) to raised the temperature of a body is given as:

Q = mCΔT

The quantity of heat required to raise the temperature of water is equal to the temperature loss by the iron.

Q water (gain) + Q iron (loss) = 0

Q water = - Q iron

42800 g ×  4.184 J/g°C × 23°C = -m × 0.444 J/g°C × -1400°C

m = 4118729.6/621.6

m = 6626 g

8 0
3 years ago
The molar enthalpy of vaporization of boron tribromide is 30.5 kj/mol, and its normal boiling point is 91°c. what is the vapor p
adell [148]
To answer this question, we will use the following equation:
<span>ln(P2/P1) = (∆Hvap/R)*((1/T1) - (1/T2)) 
</span>
Now we examine the givens of the problem and transform to standard units if required:
<span>∆Hvap = 30.5 kJ/mol 
</span>R is a constant = <span>8.314 x 10^-3 kJ K^-1 mol^-1 
T1 </span><span>= 91 celcius = 91 + 273= 364 Kelvin
</span>T2 = 20 celcius = 20 + 273 = 293 k3lvin
P1 is the standard atmospheric pressure = 760 mmHg
P2 is the value to be calculated

Substitute with these values in the equation:
ln(P2/760) = (30.5 / 8.314 x 10^-3) x ((1 / 364) - (1 / 293)) 
ln(P2/760) = - 2.4662 (Take the exponential both sides to eliminate the ln)
P2 / 760 = e^(-2.4462) = 0.0866
P2 = 0.0866 x 760 = 65.816 mmHg
5 0
4 years ago
The knowledge produced by science builds on old ideas and is constantly changing.
VikaD [51]
Yes it is always changing, as time moves on new technological advancements are made. This makes it possible for new ideas to be created. For example the depiction of an atom went through many stages throughout the years in order to find out our current final version. New scientists and new ideas can add on to older ones, making explanations that make more scientific sense.
6 0
3 years ago
How many glucose molecules are needed to make 24 acetyls in pyruvate processing?
jekas [21]

Glucose is converted into pyruvate in a process called Glycolysis which aim in production of energy for most of tissues inside our body... then pyruvate is converted into acetyl coA with the help of pyruvate dehydrogenase enzyme then this acetyl coA enters citric acid cycle for production of more energy 

One Acetyl molecule will be produced form one pyruvic acid. and two pyruvic acid molecule will be formed from one glucose molecule during glycolysis. so from

2 acetyl molecules → one glucose molecules.

For 24 acetyl molecules → ??

24*1/2 = 12.

The answer is 12 Glucose molecules.  

4 0
3 years ago
Question 8<br> What is the effective nuclear charge for a 2nd row electron in sulfur
miss Akunina [59]

Answer:

The effective nuclear charge for a 2nd row electron in Sulfur is +8

Explanation:

Zeff = Z (# of protons) - S (# of shielded electrons)

Since there are 8 electrons in the first and second rows combined, there are 8 shielding electrons.

The number of protons in Sulfur is 16.

Therefore,

Zeff = 16 - 8

Zeff = 8

(It's been awhile, so I am not 100% sure)

7 0
3 years ago
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