Answer:
The pH of 0.1 M BH⁺ClO₄⁻ solution is <u>5.44</u>
Explanation:
Given: The base dissociation constant:
= 1 × 10⁻⁴, Concentration of salt: BH⁺ClO₄⁻ = 0.1 M
Also, water dissociation constant:
= 1 × 10⁻¹⁴
<em><u>The acid dissociation constant </u></em>(
)<em><u> for the weak acid (BH⁺) can be calculated by the equation:</u></em>

<em><u>Now, the acid dissociation reaction for the weak acid (BH⁺) and the initial concentration and concentration at equilibrium is given as:</u></em>
Reaction involved: BH⁺ + H₂O ⇌ B + H₃O+
Initial: 0.1 M x x
Change: -x +x +x
Equilibrium: 0.1 - x x x
<u>The acid dissociation constant: </u>![K_{a} = \frac{\left [B \right ] \left [H_{3}O^{+}\right ]}{\left [BH^{+} \right ]} = \frac{(x)(x)}{(0.1 - x)} = \frac{x^{2}}{0.1 - x}](https://tex.z-dn.net/?f=K_%7Ba%7D%20%3D%20%5Cfrac%7B%5Cleft%20%5BB%20%5Cright%20%5D%20%5Cleft%20%5BH_%7B3%7DO%5E%7B%2B%7D%5Cright%20%5D%7D%7B%5Cleft%20%5BBH%5E%7B%2B%7D%20%5Cright%20%5D%7D%20%3D%20%5Cfrac%7B%28x%29%28x%29%7D%7B%280.1%20-%20x%29%7D%20%3D%20%5Cfrac%7Bx%5E%7B2%7D%7D%7B0.1%20-%20x%7D)





<u>Therefore, the concentration of hydrogen ion: x = 3.6 × 10⁻⁶ M</u>
Now, pH = - ㏒ [H⁺] = - ㏒ (3.6 × 10⁻⁶ M) = 5.44
<u>Therefore, the pH of 0.1 M BH⁺ClO₄⁻ solution is 5.44</u>
The Nernst equation allows us to predict the cell potential for voltaic cells under conditions other than the standard conditions of 1M, 1 atm, 25°C. The effects of different temperatures and concentrations may be tracked in terms of the Gibbs energy change ΔG. This free energy change depends upon the temperature & concentrations according to ΔG = ΔG° + RTInQ where ΔG° is the free energy change under conditions and Q is the thermodynamic reaction quotient. The free energy change is related to the cell potential Ecell by ΔG= nFEcell
so for non-standard conditions
-nFEcell = -nFE°cell + RT InQ
or
Ecell = E°cell - RT/nF (InQ)
which is called Nernst equation.
Answer : The volume of hydrogen gas at STP is 4550 L.
Explanation :
Combined gas law is the combination of Boyle's law, Charles's law and Gay-Lussac's law.
The combined gas equation is,

where,
= initial pressure of gas = 100.0 atm
= final pressure of gas at STP = 1 atm
= initial volume of gas = 50.0 L
= final volume of gas at STP = ?
= initial temperature of gas = 
= final temperature of gas at STP = 
Now put all the given values in the above equation, we get:


Therefore, the volume of hydrogen gas at STP is 4550 L.
Answer:
As the Bohr's fixed orbit gives precise information about the radial position and momentum of the orbit, it is against the Heisenberg uncertainty principle. Thus it is inferred that the Heisenberg uncertainty principle goes and the concept Bohr's fixed Orbit are opposite to each other.
Explanation:
Answer:
1 gram
Explanation:
Half life = 25 years
Starting mass = 16 grams
Time = 100 years
Number of half lives = Time / Duration of Half life = 100 / 25 = 4
After first Half life;
Remaining mass = 16 / 2 = 8 g
After Second Half life;
Remaining mass = 8 / 2 = 4 g
After Third Half life;
Remaining mass = 4 / 2 = 2 g
After Fourth Half life;
Remaining mass = 2 / 2 = 1 g