It's Synthesis, single replacement is incorrect.
Answer: The standard free energy change for a reaction in an electrolytic cell is always positive.
Explanation:
Electrolytic cells use electric currents to drive a non-spontaneous reaction forward.
Relation of standard free energy change and emf of cell

where,
= standard free energy change
n= no of electrons gained or lost
F= faraday's constant
= standard emf
= standard emf = -ve , for non spontaneous reaction
Thus 
Thus standard free energy change for a reaction in an electrolytic cell is always positive.
Answer:
Option (D)
Explanation:
Phosphorylation can be simply defined as the addition of a phosphate group to an organic and inorganic molecule. This process helps in regulating the processes that occur in the cells. It leads to the growth and development of cells and this process is efficiently carried out with the help of enzymes like kinase. It also plays an important role in transferring the signals within the cells, synthesis, and functioning of proteins within the cells, and storing as well as releasing of energy.
Thus, the correct answer is option (D).
Due to hydrogen bonding there is a formation of cage like structure called lattice in ice due to which <span> density of ice is less than that of water. Moreover, it is a known fact that density of water is maximum at 4°C.</span>