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vampirchik [111]
3 years ago
8

At 850K, 65L of gas has a pressure of 450kPa. What is the volume (in liters) if the gas is cooled to 430K and the pressure decre

ases to 325kPa?
Chemistry
1 answer:
Novosadov [1.4K]3 years ago
8 0

Answer:

V₂ =  45.53 L

Explanation:

Given data:

Initial temperature = 850 K

Initial volume = 65 L

Initial pressure = 450 KPa

Final temperature = 430 K

Final pressure = 325 KPa

Final volume = ?

Solution:

Formula:  

P₁V₁/T₁ = P₂V₂/T₂  

P₁ = Initial pressure

V₁ = Initial volume

T₁ = Initial temperature

P₂ = Final pressure

V₂ = Final volume

T₂ = Final temperature

Solution:

V₂ = P₁V₁ T₂/ T₁ P₂  

V₂ = 450 KPa× 65 L × 430 K / 850 K × 325KPa  

V₂ = 12577500 KPa .L. K / 276250 K. KPa

V₂ =  45.53 L

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The question is incomplete, here is the complete question:

Calculate the pH of a solution prepared by dissolving 0.370 mol of formic acid (HCO₂H) and 0.230 mol of sodium formate (NaCO₂H) in water sufficient to yield 1.00 L of solution. The Ka of formic acid is 1.77 × 10⁻⁴

a) 2.099

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<u>Explanation:</u>

We are given:

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Volume of solution = 1 L

To calculate the molarity of solution, we use the equation:

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To calculate the pH of acidic buffer, we use the equation given by Henderson Hasselbalch:  

pH=pK_a+\log(\frac{[salt]}{[acid]})

pH=pK_a+\log(\frac{[HCOONa]}{[HCOOH]})

pK_a = negative logarithm of acid dissociation constant of formic acid = 3.75

[HCOONa]=\frac{0.230}{1}  

[HCOOH]=\frac{0.370}{1}

pH = ?  

Putting values in above equation, we get:  

pH=3.75+\log(\frac{0.23/1}{0.37/1})\\\\pH=3.54

Hence, the pH of the solution is 3.546

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