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ozzi
3 years ago
15

Which isomer of 1-bromo-2-tert-butylcyclohexane reacts faster when refluxed with potassium tert-butoxide?Draw the structure of t

he expected major product from the faster reacting compound.
Chemistry
1 answer:
ivolga24 [154]3 years ago
8 0

Answer:

See explanation and image attached

Explanation:

The reaction of 1-bromo-2-tert-butylcyclohexane with  potassium tert-butoxide is an elimination reaction that occurs by E2 mechanism.

The E2 reaction proceeds faster when the hydrogens are in an antiperiplanar position at an angle of 180 degrees.

This is only attainable in the trans isomer of 1-bromo-2-tert-butylcyclohexane. Hence trans 1-bromo-2-tert-butylcyclohexane reacts faster with potassium tert-butoxide

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Answer:

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Explanation:

The reaction can be expressed as:

CₓHₓOₓ + nO₂ → CO₂ + H₂O

Under the assumption that there was a total combustion, all of the carbon in the reactant was combusted into CO₂, so <u>the mass of C contained in the C.H.O. compound is the same mass of C contained in 1.039 g of CO₂</u>:

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All of the hydrogens atoms in the compound ended up becoming H₂O, so <u>the mass of H contained in the C.H.O. compound is the same mass of H contained in 0.6369 g of H₂O</u>:

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0.5438 g Compound - 0.2834 g C - 0.0354 g H = 0.2250 g O

In order to determine the empirical formula, we calculate the moles of each component:

  • mol C = 0.2834 g C ÷ 12 g/mol = 0.0236 mol C
  • mol H = 0.0354 g H ÷ 1 g/mol = 0.0354 mol H
  • mol O = 0.2250 g O ÷ 16 g/mol = 0.0141 mol O

Then we divide those values by the lowest one:

0.0236 mol C ÷ 0.0141 = 1.67

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If we multiply those values by 2, we're left with the empirical formula C₃H₅O₂.

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4C₃H₅O₂ + 13O₂ → 12CO₂ + 10H₂O

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