The loss or gain of electrons
Explanation:
The loss or gain of electrons determines if an atom will become a cation or anion.
A cation is a positively charge ion
An anion is a negatively charged ion.
In an atom, we have sub-atomic particles:
Protons are the positively charged particles
Electrons are negatively charged
Neutrons carry no charges
Only electrons can be lost or gained in chemical processes that forms cations and anions.
When a neutral atom gains electron, it has more electrons than protons. This makes it negatively charged and we call it an anion.
When a neutral atom loses an electron, the number of protons is more. We call it a cation.
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Adding (S2O3)2- would affect the reaction mechanism that involves this ion. From the reaction mechanism given above, the equilibrium of step 2 would be affected. Adding the stock solution of (S2O3)2- would shift the equilibrium to the right thus making more products of the said mechanism. Also, the reaction rate of this step would occur faster than the original rate. This is based on Le Chatelier's Prinicple which states that a corresponding change would happen to the equilibrium of a reaction when pressure, concentration of the substances or temperature is changed. So, that after the addition, a color change would appear immediately because I3- would be removed slowly from solution, and would therefore be able to react with starch.