Answer:
-0.93 °C; 100.26 °C
Step-by-step explanation:
(a) Freezing point depression
The formula for the freezing point depression ΔT_f is
ΔT_f = iKf·b
i is the van’t Hoff factor: the number of moles of particles you get from a solute.
For sucrose,
Sucrose (s) ⟶ sucrose (aq)
1 mole sucrose ⟶ 1 mol particles i = 1
ΔT_f = 1 × 1.86 × 0.50
ΔT_f = 0.93 °C
T_f = T_f° - ΔT_f
T_f = 0.00 – 0.93
T_f = -0.93 °C
(b) Boiling point elevation
The formula for the boiling point elevation ΔTb is
ΔTb = iKb·b
ΔTb = 1 × 0.512 × 0.50
ΔTb = 0.256 °C
Tb = Tb° + ΔTb
Tb = 100.00 + 0.256
Tb = 100.26 °C
Answer:
Explanation:
The photo is not there :o
Answer:
330 mL of (NH₄)₂SO₄ are needed
Explanation:
First of all, we determine the reaction:
(NH₄)₂SO₄ + 2NaOH → 2NH₃ + 2H₂O + Na₂SO₄
We determine the moles of base:
(First, we convert the volume from mL to L) → 62.6 mL . 1L/1000 mL = 0.0626L
Molarity . volume (L) = 2.31 mol/L . 0.0626 L = 0.144 moles
Ratio is 2:1. Therefore we make a rule of three:
2 moles of hydroxide react with 1 mol of sulfate
Then, 0.144 moles of NaOH must react with (0.144 .1) /2 = 0.072 moles
If we want to determine the volume → Moles / Molarity
0.072 mol / 0.218 mol/L = 0.330 L
We convert from L to mL → 0.330L . 1000 mL/1L = 330 mL